The ability of metallic nanostructures to confine light at the sub‐wavelength scale enables new perspectives and opportunities in the field of nanotechnology. Making use of this unique advantage, nano‐optical trapping techniques have been developed to tackle new challenges in a wide range of areas from biology to quantum optics. In this work, starting from basic theories, we present a review of research progress in near‐field optical manipulation techniques based on metallic nanostructures, with an emphasis on some of the most promising advances in molecular technology, such as the precise control of single biomolecules. We also provide an overview of possible future research directions of nanomanipulation techniques.
Marine plastic debris is widely recognized as a global environmental issue. Small microplastic particles, with an upper size limit of 20 μm, have been identified as having the highest potential for causing damage to marine ecosystems. Having accurate methods for quantifying the abundance of such particles in a natural environment is essential for defining the extent of the problem they pose. Using an optical micro-Raman tweezers setup, we have identified the composition of particles trapped in marine aggregates collected from the coastal surface waters around the subtropical island of Okinawa. Chemical composition analysis at the single-particle level indicates dominance by low-density polyethylene, which accounted for 75% of the small microplastics analysed. The smallest microplastics identified were (2.53 ± 0.85) μm polystyrene. Our results show the occurrence of plastics at all test sites, with the highest concentration in areas with high human activities. We also observed additional Raman peaks on the plastics spectrum with decreasing debris size which could be related to structural modification due to weathering or embedding in organic matter. By identifying small microplastics at the single-particle level, we obtain some indication on their dispersion in the ocean which could be useful for future studies on their potential impact on marine biodiversity.
Plasmonic optical tweezers that stem from the need to trap and manipulate ever smaller particles using non‐invasive optical forces, have made significant contributions to precise particle motion control at the nanoscale. In addition to the optical forces, other effects have been explored for particle manipulation. For instance, the plasmonic heat delivery mechanism generates micro‐ and nanoscale optothermal hydrodynamic effects, such as natural fluid convection, Marangoni fluid convection and thermophoretic effects that influence the motion of a wide range of particles from dielectric to biomolecules. In this review, a discussion of optothermal effects generated by heated plasmonic nanostructures is presented with a specific focus on applications to optical trapping and particle manipulation. It provides a discussion on the existing challenges of optothermal mechanisms generated by plasmonic optical tweezers and comments on their future opportunities in life sciences.
Optical manipulation has attracted remarkable interest owing to its versatile and noninvasive nature. However, conventional optical trapping remains inefficient in the nanoscopic world. The emergence of plasmonics in recent years has brought a revolutionary change in overcoming limitations due to diffraction and the requirements for high trapping laser powers. Among the near-field optical trapping cavity-based systems, Fano-resonant optical tweezers have a robust trapping capability. In this work, we experimentally demonstrate sequential trapping of 20 nm particles through the use of metamaterial plasmonic optical tweezers. We investigate the multiple trapping via trap stiffness measurements for various trapping configurations at low and high incident laser intensities. Our plasmonic configuration could be used as a light-driven nanoscale sorting device under low laser excitation. Our results provide an alternative approach to trap multiple nanoparticles at distinct hotspots, enabling ways to control mass transport on the nanoscale.