The 5th sub-member in 5 Member Ordovician Majiagou Formation in Daniudi Gas Field, Ordos Basin, is deposited in an environment consisting of an ancient epicontinental sea, where very fine crystalline dolostone reservoir has developed. In this study, based on the petrological and geochemical characteristics, the genesis of the dolomite developed in M55 were studied by analyzing the properties and sources of the dolomitization fluids, and the influence of the paleogeomorphology differences on the distribution of dolostone was also discussed in order to clarify the distribution of the dolostone developed in the lime flat of the epicontinental sea. The dolostone of the M55 had a crystal structure, mainly including microcrystalline and very fine crystalline. The content of MgO and CaO in dolomite was negatively correlated, indicating that it was the result of replacement. The dolomite was dark red under cathode luminescence, and the distribution mode of rare earth elements showed the negative anomaly of Ce and Eu, indicating that the dolomitization fluid was sea-sourced fluid. The δ13C, δ18O, and 87Sr/86Sr isotope range of limestone was similar to that of Ordovician seawater in the study area, whereas the δ13C, δ18O, and 87Sr/86Sr of dolostone were obviously more positive than that of limestone. The substitute index of the salinity (Z) of the dolomitization fluid was higher than 122, which is higher than limestone (Z = 120.5), indicating that the dolomitization fluid was slightly evaporated seawater. The wormholes observed on the core and the gypsum in the penecontemporaneous period observed in the thin sections indicated that the dolostone was formed in a period when the sea level was relatively low, and it was the result of seepage–reflux dolomitization. By analyzing the correlation between the thickness of dolostone and the paleogeomorphology of the M55 of the sedimentary period, it was found that the thickness of dolostone at relatively high altitude was significantly larger than that of other areas. The development of dolostone was controlled by sea level, and the local paleogeomorphology controls the distribution of dolostone during the period of low sea level. There were many more limestone–dolostone cycles and larger cumulative thicknesses of dolostone at relatively higher topography. This study provides a theoretical basis for the prediction of the distribution of dolostone reservoirs in the carbonate tidal flat environment dominated by lime flats under the background of the ancient epicontinental sea.
The characteristics of shale micro-pore development and its main influencing factors have important theoretical guiding significance for shale gas exploration and resource evaluation. In order to clarify the micro-pore development characteristics of lower Cambrian shale and the main controlling factors of micro-pore development, we used the lower Cambrian Niutitang formation shale, in the Wenshuicun section of the Guizhou Province in southwest China. The micro-pore development characteristics of the shale in the region were studied by argon ion profile field emission scanning electron microscopy and a low-temperature liquid nitrogen adsorption and desorption experimental system. The relationship between micro-pore and kerogen maceral composition, total organic carbon (TOC) content and different mineral content was analyzed in combination with mineral and geochemical characteristics. Inorganic pores (clay mineral pores, dissolution pores and pyrite intergranular pores) and micro-fractures (clay mineral shrinkage crack, tectonic fractures and overpressure fractures) were the main type of pore developed in the shale of the Niutitang formation in the Wenshuicun section, and no organic pores had developed. The pore size of shale is usually 2–50 nm, accounting for 58.33% of shale pores, e.g. mesopores. Clay mineral content has an obvious positive correlation with macropore volume and average pore diameter, and an obvious negative correlation with micropore volume. In addition, the content of feldspar in brittle minerals has a strong negative correlation with macropore volume and average pore diameter, and a strong positive correlation with micropore volume and BET-specific surface area. TOC content and the content of different kerogen macerals have no obvious correlation with the development of shale micropores in this region. It is concluded that inorganic mineral composition is the main controlling factor of micro-pore development within lower Cambrian shale, and organic matter abundance and maceral content have little influence on the micro-pore development. This study provides a case study for the characteristics of micropores in lower Cambrian shale in China.
The hydrothermal fluid–carbonate rock reaction is frequently regarded to occur in deep-burial diagenesis, and the hydrothermal dissolution is usually distributed and takes place along the faults. Previous studies have suggested that there was hydrothermal fluid activity locally in the Permian Qixia Formation in Sichuan Basin, likely related to the Emeishan basalt eruption. However, the effect of hydrothermal fluids on the carbonate rocks of the Qixia Formation in the central uplift of Sichuan Basin is still unclear. Based on the characteristics and geochemical parameters of the diagenetic minerals, this study aims to reveal the diagenetic alteration related to the hydrothermal fluid–rock reaction in the Qixia Formation and reestablish the diagenetic evolution by using the timing of diagenetic mineral precipitation. The methods include petrographic observation; trace and rare earth element (REE) analysis; C, O and Sr isotope measurement; fluid inclusion temperature measurement and cathodoluminescence analysis. According to the petrographic characteristics, the dolostones are mainly of crystalline structure, namely fine-medium crystalline dolostone, meso-coarse crystalline dolostone, and coarse crystalline dolostone, with the cathodoluminescence color becoming brighter in that order. The limestones from the Qixia Formation are of the bioclastic limestone type, with no cathodoluminescence color. Compared with dolostones, limestones have higher Sr content, lower Mn content, and heavier oxygen isotopes. With the crystalline size of dolostone becoming coarser, the oxygen isotopes of dolostones tend to become lighter. The meso-coarse crystalline dolostone has the highest Mn content and negative carbon isotope. Both limestones and dolostones have an obvious positive Eu anomaly in the Qixia Formation. However, the REE patterns of fine-medium crystalline dolostones are very different from those of meso-coarse crystalline dolostones. It is credible that there were two periods of hydrothermal fluid charging, with different chemical compositions. The first period of hydrothermal fluids could laterally migrate along the sequence boundary. Fine-medium crystalline dolostones were almost completely distributed below the sequence boundary and were dolomitized during the shallow burial period. As products of the hydrothermal fluid–dolostone reaction, the saddle-shaped dolomites in the meso-coarse crystalline dolostones were the evidence of the second period of hydrothermal fluids. As a result, the dolomitization model was established according to the timing of diagenetic mineral precipitation, which can improve that the geological understanding of the effect of hydrothermal fluid activities on the carbonate rocks in the Qixia Formation.
The Shaximiao Formation in the Southwestern Sichuan Basin is rich in natural gas resources, but the genetic types of channel sandbodies remain unclear. This study investigated the sedimentary characteristics and sandbody genetic types of the Jurassic Shaximiao Formation using well core, logging, and reservoir property data. The results revealed that: (1) The Shaximiao Formation is predominated by shallow-water delta front facies, with delta plain facies present only in the Sha-1 Member. Lithologically, it exhibits a “mudstone-overlying-sandstone” pattern with channel sedimentary sequences portraying normal grading and various microfacies. (2) The sandstones of the Shaximiao Formation developed seven types of lithofacies. Based on the characteristics of lithofacies associations, six genetic types of sandbodies, i.e., deeply incised abrupt-transition, deeply incised gradual-transition, growth gradual-transition, progradational superimposed, progradational mouth bar, and suspension accretion sandbodies are recognized. The deeply incised abrupt-transition and deeply incised gradual-transition sandbodies have the best reservoir physical properties, while the suspension accretion sandbody has the worst. (3) These genetic types of sandbodies are controlled by the relative position of the channels and their relation to mouth bars, with reservoirs in deeply incised abrupt-transition and deeply incised gradual-transition sandbodies developed in the delta plain. (4) High-quality reservoirs are found in deeply incised abrupt-transition and gradual-transition sandbodies, where sedimentary processes strongly influence reservoir physical properties. This study provides new insights into the relationship between tight sandstone reservoirs and channel sandbody genetic types, offering guidance for exploration and development in similar regions.