Among perovskites, the research on cesium lead iodides (CsPbI₃) has attracted a large research community, owing to their all-inorganic nature and promising solar cell performance. Typically, the CsPbI₃ solar cell devices are prepared at various heterojunctions, and working at fluctuating temperatures raises questions on the material stability-related performance of such devices. The fundamental studies reveal that their poor stability is due to a lower side deviation from Goldschmidt’s tolerance factor, causing weak chemical interactions within the crystal lattice. In the case of organic–inorganic hybrid perovskites, where their stability is related to the inherent chemical nature of the organic cations, which cannot be manipulated to improve the stability drastically whereas the stability of CsPbI₃ is related to surface and lattice engineering. Thus, the challenges posed by CsPbI₃ could be overcome by engineering the surface and inside the CsPbI₃ crystal lattice. A few solutions have been proposed, including controlled crystal sizes, surface modifications, and lattice engineering. Various research groups have been working on these aspects and had accumulated a rich understanding of these materials. In this review, at first, we survey the fundamental aspects of CsPbI₃ polymorphs structure, highlighting the superiority of CsPbI₃ over other halide systems, stability, the factors (temperature, polarity, and size influence) leading to their phase transformations, and electronic band structure along with the important property of the defect tolerance nature. Fortunately, the factors stabilizing the most effective phases are achieved through a size reduction and the efficient surface passivation on the delicate CsPbI₃ nanocrystal surfaces. In the following section, we have provided the up-to-date surface passivating methods to suppress the non-radiative process for near-unity photoluminescence quantum yield, while maintaining their optically active phases, especially through molecular links (ligands, polymers, zwitterions, polymers) and inorganic halides. We have also provided recent advances to the efficient synthetic protocols for optically active CsPbI₃ NC phases to use readily for solar cell applications. The nanocrystal purification techniques are challenging and had a significant effect on the device performances. In part, we summarized the CsPbI₃-related solar cell device performances with respect to the device fabrication methods. At the end, we provide a brief outlook on the view of surface and lattice engineering in CsPbI₃ NCs for advancing the enhanced stability which is crucial for superior optical and light applications.

Precise control of quantum structures in hybrid nanocrystals requires advancements in scientific methodologies. Here, on the design of tunable CsPbBr₃/Cs₄PbBr₆ quantum dots are reported by developing a unique discrete phase transformation approach in Cs₄PbBr₆ nanocrystals. Unlike conventional hybrid systems that emit solely in the green region, this current strategy produces adjustable luminescence in the blue (450 nm), cyan (480 nm), and green (510 nm) regions with high photoluminescence quantum yields up to 45%, 60%, and 85%, respectively. Concentration‐dependent studies reveal that phase transformation mechanisms and the factors that drive CsBr removal occur at lower dilutions while the dissolution–recrystallization process dominates at higher dilutions. When the polymer‐CsPbBr₃/Cs₄PbBr₆ integrated into a field‐effected transistor the resulting phototransistors featured enhanced photosensitivity exceeding 10⁵, being the highest reported for an n‐type phototransistor, while maintaining good transistor performances as compared to devices consisting of polymer‐CsPbBr₃ NCs.

Growth kinetics involved in spontaneous random clustering of perovskite precursors to a particular cesium–lead–bromide (Cs–Pb–Br) nanocrystal (NC) is a poorly understood phenomenon and its spectroscopic investigation is highly challenging. There is scarcely any method that has been optimized yet in which perovskites and their related NCs of a particular size can be grown, viewed, or tuned to another by reaction handling. Here, for the first time, we shed light on the largely overlooked process of growth kinetics of these transformations throughout the reaction trajectory of anionic [PbBr_x]ⁿ⁻ crystallization dictated by Cs⁺ cation and report a simple and direct approach to control the metathesis reaction between two precursors (specifically Cs⁺- and PbBr₂-associated oligomeric complexes) in one solvent at room temperature to monitor the NC growth characteristics in a stepwise manner even in the early stages of nucleation. Altering the molar ratio of the two precursors up to a factor of 10 leads to the formation of three prominent phases (CsPbBr₃, Cs₄PbBr₆, CsBr) as dictated by Cs⁺ to trigger distinct morphological forms (nanobelts, nanoplatelets, rhombohedral NCs, pseudo-rhombic NCs, spherical CsBr NCs, cubic CsBr NCs) including a transient phase that is formed out of linearly self-assembled CsPbBr₃ clusters. Our results pave the way towards understanding spontaneous crystallization to develop well-defined, hassle-free routes for diverse perovskite NCs in a simple yet controlled manner.

Electrically conductive hydrogels are gaining attention owing to their applications in biosensing, cellular interfaces, and tissue engineering. However, conventional hydrogels often lack adequate electrical conductivities. Here, we present two novel conductive alginate-based hydrogels designed for extrusion-based 3D bioprinting: (i) covalently synthesized alginate–polypyrrole (alginate–PPy) via EDC/NHS-mediated conjugation with 3-aminopropyl pyrrole, and (ii) nanoparticle-reinforced alginate blended with polypyrrole nanoparticles (alginate@PPy-NP). Both systems exhibited shear-thinning behavior, tunable viscoelasticity, and excellent printability. Alginate@PPy-NP demonstrated superior compressive strength and shape fidelity, whereas alginate–PPy showed enhanced elastic moduli (G′/G″), reflecting a more uniform gel network. Electrical conductivity increased with increasing pyrrole content in both formulations. Optimization of the composition and printing conditions enabled the fabrication of fibroblast-laden constructs with high structural integrity. This work highlights the potential of alginate–polypyrrole hydrogels as customizable, conductive bioinks for 3D bioprinting in regenerative medicine.

Electrically conductive hydrogels are gaining attention for their applications in biosensing, cellular interfaces, and tissue engineering. However, conventional hydrogels often lack adequate electrical conductivity. Here, we present two novel conductive alginate-based hydrogels designed for extrusion-based 3D bioprinting: (i) covalently synthesized alginate-polypyrrole (alginate-PPy) via EDC/NHS-mediated conjugation with 3-aminopropyl pyrrole and (ii) nanoparticle-reinforced alginate blended with polypyrrole nanoparticles (alginate@PPy-NP). Both systems exhibit shear-thinning behavior, tunable viscoelasticity, and excellent printability. Alginate@PPy-NP demonstrated superior compressive strength and shape fidelity, whereas alginate-PPy showed enhanced elastic moduli (G′/G″), reflecting a more uniform gel network. The electrical conductivity increased with increasing pyrrole content in both formulations. Optimization of the composition and printing conditions enabled the fabrication of fibroblast-laden constructs with high structural integrity. This work highlights the potential of alginate-polypyrrole hydrogels as customizable, conductive bioinks for 3D bioprinting in regenerative medicine.