Organic thermoelectric (TE) materials have been widely investigated due to their good stability, easy synthesis, and high electrical conductivity. Among them, polyaniline/carbon nanotubes (PANI/CNTs) composites have attracted significant attention for pursuing enhanced TE properties to meet the demands of commercial applications. In this review, we summarize recent advances in versatile PANI/CNTs composites in terms of the dispersion methods of CNTs (such as the addition of surfactants, mechanical grinding, and CNT functional group modification methods), fabrication engineering (physical blending and in-situ polymerization), post-treatments (solvent treatments to regulate the doping level and microstructure of PANI), and multi-components composites (incorporation of other components to enhance energy filtering effect and Seebeck coefficient), respectively. Various approaches are comprehensively discussed to illustrate the microstructure modulation and conduction mechanism within PANI/CNTs composites. Furthermore, we briefly give an outlook on the challenges of the PANI/CNTs composites for achieving high performance and hope to pave a way for future development of high-performance PANI/CNTs composites for sustainable energy utilization.
29 March 2024 in ACS Applied Materials & Interfaces
We have demonstrated a photoelectrochemical solar-blind ultraviolet (UV) detector based on SrTiO 3 (STO) nanocrystalline film in this work. The assembled UV detector presents a high on/off ratio of about 6433 under periodic UV irradiation, a high photocurrent density of 220.6 μ A cm −2 , and a fast response time of 9 ms. By introducing a block layer (BL) on fluorine-doped tin oxide substrate, the response and decay times are shortened to 6 ms and 8 ms, respectively. The BL plays a crucial part in hindering the recombination of electrons from electrolyte carriers and avoiding short circuits. Due to its excellent light capture capability, the detector based on SrTiO 3 nanocrystalline exhibits high sensitivity to weak UV light (5 μ W cm −2 ). Moreover, the detector also exhibits visible-blind characteristics and a good linear response.