The antioxidant activity of the phenolic compounds present in industrial black liquors obtained from the two cooking processes (kraft and sulphite) used in Portugal to produce Eucalyptus globulus pulp was evaluated. The black liquors treated at several pH values were extracted with ethyl acetate. Phenolic fractions were further separated by liquid chromatography of the crude extracts of kraft liquor at pH = 6 and sulphite liquor at the original pH. Total phenolic content was determined in terms of gallic acid equivalents (Folin-Ciocalteu colorimetric method), and the antioxidant activity in the crude extracts at several pH values and in the separated fractions was measured using the DPPH test for radical scavenging capacity. The total phenolic content of crude extracts and separated fractions ranged from 92.7 to 181.6 and from 91.6 to 1,099.6 mg GAE/g, respectively, while the antioxidant activity index (AAI) ranged from 2.20 to 3.41 and from 2.21 to 11.47 respectively, showing very strong antioxidant activity in all studied cases. The fractions separated by column chromatography were submitted to mass spectrometry analysis and the results were compared to others in the literature of natural products, mainly from Eucalyptus, and the characteristic bands of functional groups were identified by ¹H-NMR and FTIR. These methods allowed the identification of 17 phenolic compounds.

Countries unaccustomed to wildfires are currently experiencing wildfire as a new climate-change reality. Understanding how fire ignition and propagation are correlated with temperature, orography, humidity, wind, and the mixture and age of individual plants must be considered when designing prevention strategies. While wildfire prevention focuses on fire ignition avoidance, firefighting success depends on early ignition detection, meaning that, in either case, ignition plays a major role. The current case study considered three Portuguese municipalities that annually observe frequent fire ignitions (Tomar, Ourém, and Ferreira do Zêzere) as the testing ground for the Modernized Dynamic Ignition Risk (MDIR) strategy, thus evaluating the efficiency of MDIR and the efficacy of the variables used. This methodology uses geographic information systems technology sustained by open-source satellite imagery, along with the Habitat Risk Assessment model from the InVEST software package, as drivers for the MDIR application. The MDIR approach grants frequent update capabilities and fully open-sourced high ignition risk area identification, producing monthly ignition risk maps. The advantage of using this method is the ease of adaptation to any current monitoring strategy, awarding further efficiency and efficacy in reducing ignitions. The approach delivered adequate results in estimating ignitions for the three Portuguese municipalities, achieving, for several months, prediction accuracy percentages of over 70%. For the studied area, MDIR clearly identifies areas of high ignition risk and delivers an average of 62% success in predicting ignitions, thus showing potential for analyzing the impact of policy implementation and monitoring through the strategy design.