The exploration of sustainable energy utilization requires the implementation of advanced electrochemical devices for efficient energy conversion and storage, which are enabled by the usage of cost-effective, high-performance electrocatalysts. Currently, heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications. Compared to conventional catalysts, atomically dispersed metal atoms in carbon-based catalysts have more unsaturated coordination sites, quantum size effect, and strong metal–support interactions, resulting in exceptional catalytic activity. Of these, dual-atomic catalysts (DACs) have attracted extensive attention due to the additional synergistic effect between two adjacent metal atoms. DACs have the advantages of full active site exposure, high selectivity, theoretical 100% atom utilization, and the ability to break the scaling relationship of adsorption free energy on active sites. In this review, we summarize recent research advancement of DACs, which includes (1) the comprehensive understanding of the synergy between atomic pairs; (2) the synthesis of DACs; (3) characterization methods, especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy; and (4) electrochemical energy-related applications. The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules, such as oxygen reduction reaction, CO₂ reduction reaction, hydrogen evolution reaction, and N₂ reduction reaction. The future research challenges and opportunities are also raised in prospective section.

Aiming to solve the problem of the low path-tracking accuracy of mobile robots in agricultural environments, the authors of this paper propose a path-tracking method for agricultural machinery based on variable look-ahead distance. A kinematic model of the four wheel independent steering–four wheel independent drive (4WIS–4WID) structure based on pure pursuit was constructed to obtain the functional equation of the current position and the four-wheel steering angle. The fuzzy controller, which takes the lateral deviation and heading deviation as input and the look-ahead distance in a pure pursuit model as output, was designed to obtain the look-ahead distance that changes dynamically with the deviation of mobile agricultural machinery. The path-tracking performance of 4WIS–4WID agricultural machinery in three scenarios (1 m, −90°; 1 m, 0°; and 0 m, 90°) with different initial deviations was tested using a pure pursuit model based on a variable look-ahead distance. The obtained field test results showed an average deviation of 19.7 cm, an average tracking time of 5.1 s, an average stability distance of 203.9 cm, and a steady state deviation of 3.1 cm. The results showed that the proposed method presents a significant path-tracking performance advantage over a fixed look-ahead distance pure tracking model and can be a reference for high-quality path-tracking methods in automatic navigation research.

The current research on path tracking primarily focuses on improving control algorithms, such as adaptive and predictive models, to enhance tracking accuracy and stability. To address the issue of low tracking accuracy caused by variable-curvature paths in automatic navigation within agricultural environments, this study proposes a fuzzy control-based path-tracking method. Firstly, a pure-pursuit model and a kinematic model were established based on a Four-Wheel Independent Steering and Four-Wheel Independent Driving (4WIS-4WID) structure. Secondly, a fuzzy controller with three inputs and one output was designed, using the lateral deviation, d_e; heading deviation, θ_e; and bending degree, c, of the look-ahead path as the input variables. Through multiple simulations and adjustments, 75 control rules were developed. The look-ahead distance, Ld, was obtained through fuzzification, fuzzy inference, and defuzzification processes. Next, a speed-control function was constructed based on the agricultural machinery’s pose deviations and the bending degree of the look-ahead path to achieve variable speed control. Finally, field tests were conducted to verify the effectiveness of the proposed path-tracking method. The tracking experiment results for the two types of paths indicate that under the variable-speed dynamic look-ahead distance strategy, the average lateral deviations for the variable-curvature paths were 1.8 cm and 3.3 cm while the maximum lateral deviations were 10.1 cm and 10.5 cm, respectively. Compared to the constant-speed fixed look-ahead pure-pursuit model, the average lateral deviation was reduced by 56.1% and the maximum lateral deviation by 50.4% on the U-shaped path. On the S-shaped path, the average lateral deviation was reduced by 56.0% and the maximum lateral deviation by 58.9%. The proposed method effectively improves the path-tracking accuracy of agricultural machinery on variable-curvature paths, meeting the production requirements for curved operations in agricultural environments.

To solve the low accuracy of image feature matching in horticultural robot visual navigation, an innovative and effective image feature matching algorithm was proposed combining the improved Oriented FAST and Rotated BRIEF (ORB) and Lucas–Kanade (LK) optical flow algorithm. First, image feature points were extracted according to the adaptive threshold calculated using the Michelson contrast. Then, the extracted feature points were uniformed by the quadtree structure, which can reduce the calculated amount of feature matching, and the uniform ORB feature points were roughly matched to estimate the position of the feature points in the matched image using the improved LK optical flow. Finally, the Hamming distance between rough matching points was calculated for precise matching. Feature extraction and matching experiments were performed in four typical scenes: normal light, low light, high texture, and low texture. Compared with the traditional algorithm, the uniformity and accuracy of the feature points extracted by the proposed algorithm were enhanced by 0.22 and 50.47%, respectively. Meanwhile, the results revealed that the matching accuracy of the proposed algorithm increased by 14.59%, whereas the matching time and total time decreased by 39.18% and 44.79%, respectively. The proposed algorithm shows great potential for application in the visual simultaneous localization and mapping (V-SLAM) of horticultural robots to achieve higher accuracy of real-time positioning and map construction.

This paper proposes a path-tracking method for agricultural vehicles based on the 4WIS-4WID structure and fuzzy control to improve the operation performance of agricultural machinery in the greenhouse. The influential model of two critical parameters, α and R, on the position correction is obtained based on the relationship analysis between the traditional pure pursuit model and the vehicle structure. Based on aiming pursuit, the relationship equation between the position deviation, lateral deviation d, and heading deviation θ is established. A two-input and two-output fuzzy controller is designed, and the lateral deviation d and heading deviation θ are the input variables. Values of α and R are obtained after fuzzification, fuzzy inference, and defuzzification, and a validated MATLAB model is used to simulate different scenarios. Results of the tests show that the steady-state error of path tracking based on fuzzy control pursuit is between 35 and 51 mm, and the stability distance is between 1661 and 3052 mm for straight path tracking in four initial states. The rectangular corners have the highest inaccuracy. The results of fuzzy control pursuit show a significant improvement in path-tracking performance that can influence vehicle navigation capability in the greenhouse.

A pure pursuit method based on an improved sparrow search algorithm is proposed to address low path-tracking accuracy of intelligent agricultural machinery in complex farmland environments. Firstly, we construct a function relating speed to look-ahead distance and develop a fitness function based on the prototype’s speed and pose deviation. Subsequently, an improved sparrow search algorithm (ISSA) is employed to adjust the pure pursuit model’s speed and look-ahead distance dynamically. Finally, improvements are made to the initialization of the original algorithm and the position update method between different populations. Simulation results indicate that the improved sparrow search algorithm exhibits faster convergence speed and better capability to escape local extrema. The real vehicle test results show that the proposed algorithm achieves an average lateral deviation of approximately 3 cm, an average heading deviation below 5°, an average stabilization distance under 5 m, and an average navigation time of around 46 s during path tracking. These results represent reductions of 51.25%, 30.62%, 49.41%, and 10.67%, respectively, compared to the traditional pure pursuit model. Compared to the pure pursuit model that only dynamically adjusts the look-ahead distance, the proposed algorithm shows reductions of 34.11%, 24.96%, 32.13%, and 11.23%, respectively. These metrics demonstrate significant improvements in path-tracking accuracy, pose correction speed, and path-tracking efficiency, indicating that the proposed algorithm can serve as a valuable reference for path-tracking research in complex agricultural environments.