Lithium-ion batteries (LIBs) are undeniably the most promising system for storing electric energy for both portable and stationary devices. A wide range of materials for anodes is being investigated to mitigate the issues with conventional graphite anodes. Among them, TiO₂ has attracted extensive focus as an anode candidate due to its green technology, low volume fluctuations (<4%), safety, and durability. In this review, the fabrication of different TiO₂ nanostructures along with their electrochemical performance are presented. Different nanostructured TiO₂ materials including 0D, 1D, 2D, and 3D are thoroughly discussed as well. More precisely, the breakthroughs and recent developments in different anodic oxidation processes have been explored to identify in detail the effects of anodization parameters on nanostructure morphology. Clear guidelines on the interconnected nature of electrochemical behaviors, nanostructure morphology, and tunable anodic constraints are provided in this review.

Recently, lithium-ion batteries (LIBs) have been widely employed in automobiles, mining operations, space applications, marine vessels and submarines, and defense or military applications. As an anode, commercial carbon or carbon-based materials have some critical issues such as insufficient charge capacity and power density, low working voltage, deadweight formation, short-circuiting tendency initiated from dendrite formation, device warming up, etc., which have led to a search for carbon alternatives. Transition metal oxides (TMOs) such as NiO as an anode can be used as a substitute for carbon material. However, NiO has some limitations such as low coulombic efficiency, low cycle stability, and poor ionic conductivity. These limitations can be overcome through the use of different nanostructures. This present study reviews the integration of the electrochemical performance of binder involved nanocomposite of NiO as an anode of a LIB. This review article aims to epitomize the synthesis and characterization parameters such as specific discharge/charge capacity, cycle stability, rate performance, and cycle ability of a nanocomposite anode. An overview of possible future advances in NiO nanocomposites is also proposed.