Titanium (Ti) and its alloys have been widely employed in aeronautical, petrochemical, and medical fields owing to their fascinating advantages in terms of their mechanical properties, corrosion resistance, biocompatibility, and so on. However, Ti and its alloys face many challenges, if they work in severe or more complex environments. The surface is always the origin of failure for Ti and its alloys in workpieces, which influences performance degradation and service life. To improve the properties and function, surface modification becomes the common process for Ti and its alloys. The present article reviews the technology and development of laser cladding on Ti and its alloys, according to the cladding technology, cladding materials, and coating function. Generally, the laser cladding parameters and auxiliary technology could influence the temperature distribution and elements diffusion in the molten pool, which basically determines the microstructure and properties. The matrix and reinforced phases play an important role in laser cladding coating, which can increase the hardness, strength, wear resistance, oxidation resistance, corrosion resistance, biocompatibility, and so on. However, the excessive addition of reinforced phases or particles can deteriorate the ductility, and thus the balance between functional properties and basic properties should be considered during the design of the chemical composition of laser cladding coatings. In addition, the interface including the phase interface, layer interface, and substrate interface plays an important role in microstructure stability, thermal stability, chemical stability, and mechanical reliability. Therefore, the substrate state, the chemical composition of the laser cladding coating and substrate, the processing parameters, and the interface comprise the critical factors which influence the microstructure and properties of the laser cladding coating prepared. How to systematically optimize the influencing factors and obtain well-balanced performance are long-term research issues.

In this paper, the microstructure and properties of a Ti/Mg alloy clad plate manufactured by explosive welding were studied. The bonding interface was inspected by ultrasonic examination (US). The microstructure and the composition of the clad were characterized by OM and SEM. Properties were inspected by tensile test, shearing test, microhardness test and electrochemical corrosion. The results showed that the bonding interface of the clad plate was made up of straight areas and wavy areas. In straight areas, element diffusion occurred across the bonding interface. Additionally, in wavy areas, a melting zone occurred in the Mg alloy layer near to the bonding interface. Lots of light particles embedded on the melting zone. Tensile test results were comparable with the Ti sheet and the ultimate tensile strength of the clad plate demonstrated an 18% increase. The shearing strength of the clad plate was about 68–87 MPa. The microhardness of the clad plate was higher than that of the original sheets from the interface to 300 μm away. At over 300 μm, the microhardness of the clad plate decreased and approached the original sheets. Compared with the straight area, the hardness of the Mg alloy layer in the wavy area close to the interface increased by 12%. Corrosion results showed that the corrosion potential (E_corr) absolute value of the clad plate increased by 24%, and the corrosion current density (i_corr) value was 4 orders of magnitude lower, compared with the Mg alloy sheet. It was clear that the corrosion resistance of the clad plate was higher than that of the Mg alloy sheet. Cladding Mg alloy and Ti by explosive welding would improve the industrial applications of magnesium materials.

As a hard and brittle material, the processing of C_f/SiC ceramic matrix composites (CMCs) faces significant challenges, especially in the processing of small-sized shapes. To address this challenge, laser processing with gas-assisted nanosecond laser (GNL) and waterjet-guided nanosecond laser (WNL) modes were applied to fabricate thin kerfs in the C_f/SiC composite. The surface morphology, microstructure, and chemical composition of the processed C_f/SiC composite were investigated comparatively. The results revealed that the coupling of helium in the GNL mode laser processing could make full use of the laser energy, but resulted in spattering in the kerf margin and a recast layer in the kerf surface, accompanied by obvious oxidation, while the coupling of the waterjet in the WNL mode laser processing decreased the oxidation significantly and removed the remelting debris, which produced a clear and flat kerf surface. Due to the taper caused by laser energy dissipation, the single-path laser processing in the C_f/SiC composite had a limited depth. The maximum depth of the kerf prepared by single-path laser processing with the GNL mode was about 328 μm, while that with the WNL mode was about 302 μm. The multi-path laser processing with the GNL and WNL modes could fabricate a through kerf in the C_f/SiC composite, but the coupling medium obviously influenced the surface morphology and microstructure of the underlying region. The kerf surface prepared by the GNL mode had a varied surface morphology, which transited from the top layer, covered with oxide particles and some cracks, to the bottom layer, featured with micro-grooves and small oxides. The kerf surface prepared by the WNL mode had a consistently smooth and clean morphology featured with broken carbon fiber and residual SiC matrix. The slow laser energy dissipation and open environment in the GNL mode resulted in a bigger HAZ and relatively serious oxidation, which caused local phase transformation and microstructure degradation. The isolation condition and rapid cooling in the WNL mode decreased the HAZ and restrained the oxidation, almost keeping the original microstructure. The thicknesses of the HAZ in the GNL- and WNL-processed C_f/SiC composite were about 200 μm and 100 μm, respectively. The WNL-processed C_f/SiC composite had a lower oxidation and thermal damage surface, which is instructive for the processing of the C_f/SiC composite.