In this paper, the anionic surfactant sodium dodecyl sulfate (SDS) and the bio-surfactant rhamnolipid are mixed to achieve micellar-enhanced ultrafiltration, and the associated aniline removal efficiency is investigated. The impacts of five factors, including the mixing ratio of the SDS concentration to the rhamnolipid concentration, the pH, the salinity, the operating pressure, and the aniline concentration in the feed solution, on the aniline rejection and the membrane permeation flux are explored. The aniline rejection mechanism of the rhamnolipid mixture surfactant is analyzed. This study shows that the effect of these factors on the aniline rejection is in the order of pH > mixing ratio > operating pressure > aniline concentration > salinity; the factors that affect the membrane permeation flux are in the order of mixing ratio > operating pressure > salinity > pH > aniline concentration. Under the optimal test conditions (i.e., SDS:rhamnolipid = 8:2, pH = 5, salinity = 250 mmol/L, operating pressure = 3.5 bar, aniline concentration = 1.5 mM), the verification test results showed an aniline rejection of 78.36%.
Triclosan has been widely used as addition ingredient in personal care and medical antibacterial products, and the increasing amounts of triclosan discharged in aquatic environments pose a potential risk to aquatic ecological systems. In this study, we investigated the effects of exposure to varying triclosan concentrations on the growth, chlorophyll fluorescence and antioxidant enzyme activity of Chlorella vulgaris. The results showed that low-concentration triclosan (<0.75 mg/L) can stimulate the growth of Chlorella vulgaris, whereas 1.05 mg/L triclosan exhibited significant inhibition. Low-concentration triclosan (<0.75 mg/L) could improve the tolerance and utilization ability of Chlorella vulgaris in relation to strong light. We observed a significant increase in the malondialdehyde content of Chlorella vulgaris exposed to 1.05 mg/L triclosan. The intracellular superoxide dismutase and catalase (CAT) activities of Chlorella vulgaris exposed to triclosan were higher than the control groups, and the increase in this activity was positively correlated with the concentration of triclosan. The results also showed that excessive H2O2 may in turn damage the CAT structure and eventually inactivate CAT activity when Chlorella vulgaris is exposed to 1.05 mg/L triclosan. This study provided a theoretical basis which can be used to evaluate the ecological risk of triclosan in the aquatic environment.
Urban stormwater management is essential to improve the management of floodwaters in municipalities in urban areas. However, relying on sponge city options for site planning in an attempt to decrease the impacts of flooding is challenging due to the magnitude of flooding in urban China. The merits of exfiltration technology being used in Canada are described as having significant potential; this technology encourages passage from the stormwater pipe down to a second, lower pipe, to facilitate exfiltration to the vadose zone and, ultimately, to replenish groundwater. For example, for a small urban catchment, stormwater runoff from a 2-h long, 5-yearly storm, is demonstrated as being able to exfiltrate approximately 53% of the stormwater. Overall, the potential exists to exfiltrate stormwater from the lower pipe and it is estimated that 71% of the water entering the storm sewer is exfiltrated to the vadose zone, for a small catchment. The exfiltration pipe technology increases groundwater recharge which provides an opportunity to help manage subsidence in China. However, attention must be paid to the quality of the infiltrating water since, as true for any sponge city initiative, poor quality infiltrating water may deteriorate the quality of the groundwater.
1 May 2016 in Journal of Environmental Engineering
In this study, a two-stage fractional programming (TSFP) method is developed for supporting municipal solid waste (MSW) management under uncertainty. The model can not only balance two conflicting objectives through converting a multiobjective problem into a ratio one, but also can analyze multistage decision effects when promised policy targets are violated. Moreover, the TSFP model can facilitate dynamic analysis of capacity expansions for waste management facilities. The developed method is applied to a case study of long-term MSW management planning. The solutions obtained from TSFP can provide desired waste-allocation schemes and capacity-expansion plans under different policy scenarios. The results allow in-depth analyses in terms of conflicting objectives, policy scenarios, and capacity expansions.
A mixture of the environmentally friendly biosurfactants rhamnolipids and sophorolipids was used as a source of micelles in this study. The Box-Behnken design and response surface methodology was used to investigate the influence of factors on micellar-enhanced ultrafiltration (MEUF). Simulated Cd-containing wastewater was used for testing. Based on single-factor experiments, the initial Cd2+ concentration, biosurfactant mixing ratio (α) and pH were chosen as influential variables, and both the Cd2+ rejection coefficient and permeation flux were used as responses. A predictive model based on a quadratic polynomial regression equation was established to determine the optimized enhanced ultrafiltration conditions for Cd. The results show that the regression equation is extremely significant and fits the data accurately. The optimal enhanced ultrafiltration conditions are as follows: initial Cd2+ concentration of 10.0 mg/L, α of 0.30 and pH of 9.58. Under these conditions, the rejection coefficient and the permeation flux of Cd2+ are 99.14% and 37.36 L/m2·h, respectively. The experimental results confirm that the experimental values agree well with the values predicted by the model. Further, these results provide theoretical support for using MEUF to treat heavy metal-containing wastewater when biosurfactants are used for micelle formation.