The corrosion–wear coupling damage failure of 8Cr4Mo4V bearing steel under marine atmospheric conditions significantly limits aeroengine bearing applications. The present work aims to investigate the evolution of the corrosion–wear properties of 8Cr4Mo4V bearing steel at varied corrosion intervals and estimate the corrosion–wear interaction (CWI) effect. Neutral salt spray tests combined with tribological experiments were employed to explore the effect of corrosion on wear and the influence of wear on corrosion, and a quantitative characterization method of corrosion–wear interactions was proposed by establishing the component relationships of material losses in the corrosion–wear process. The results indicate that the corrosion rates initially increase and then decrease, ultimately resulting in a pattern characterized by predominant total corrosion and nested localized corrosion. The corroded surfaces tremendously influence the friction coefficient curves at the third stage, and a synergistic acceleration effect exists in the CWI behavior of 8Cr4Mo4V bearing steel under the action of corrosion and wear. A sample corroded for 6 h displayed the significant facilitative effect of corrosion on wear, exhibiting the highest CWI ratio and a greater total mass loss primarily attributed to corrosion. This study offers a significant reference for the quantitative assessment of the tribo-corrosion properties of bearings in a marine atmospheric environment.
The influence of elements in steel on anode plasma electrolytic boriding has been studied. The modified layers and surfaces on steel samples were analyzed by a scanning electron microscope, an X-ray diffractometer, a surface profiler, a microhardness tester, and a ball-disc tribometer. With 1045 steel as the control group, the same treatment parameters (treatment with 5 min, 200 V of voltage, 5% boric acid, and 10% ammonium chloride) were implemented on various steel substrates. It was found that a low content of carbon would hinder the penetration of boron, and other metallic elements can improve the mircrohardness gradient and decrease the wear-rate. Chromium and manganese can increase the maximum microhardness than treated 1045 by about 15%, but have a detrimental effect on surface flatness. Nevertheless, manganese has the ability to rapidly create a layer of oxide that enhances the tribological characteristics, leading to a remarkably low average friction coefficient of 0.26 for 1046 steel. The presence of molybdenum in the element composition of 4140 steel results in a notable enhancement of surface properties, namely in terms of wear resistance, with a minimum wear-rate 2.1 × 10−6 g/Nm for 4140 steel. Nickel does not appear to have a notable impact on the surface characteristics of the modified samples.
In this research, high-performance ZnAl-layered double hydroxides (ZnAl-LDHs) with different Zn2+ concentrations were prepared on the surface of an anodized 1060 aluminum alloy using the in situ growth method, and the influence of Zn2+ concentration on corrosion resistance and tribological behavior was further explored. The surface morphology, element distribution, phase composition, and mechanical performance of ZnAl-LDHs/anodic aluminum oxide (AAO) composite coatings were tested and analyzed. Subsequently, the investigation of the anti-corrosion properties and tribological behavior of as-prepared composite coatings and AAO were conducted experimentally. The results show that with the increase in Zn2+ concentration, the thickness and bonding strength of the coatings gradually increase, and the hardness progressively decreases. The ZnAl-LDHs/AAO composite coating with a Zn2+ concentration of 0.3 mol/L exhibits the best anti-corrosion ability, which has the minimum corrosion current density of 2.435 × 10−9 A/cm2. This can be attributed to the uniform and compact ZnAl-LDH films where the porous structure of the AAO is well sealed. Moreover, the excellent friction-reduction and anti-wear properties of ZnAl-LDHs/AAO composite coatings with larger Zn2+ concentrations are verified using a ball-on-disc rotating wear tester under dry wear. A reasonable mechanism for improving tribological properties of resulting ZnAl-LDHs/AAO composite coatings is proposed.