To study the full counting statistics of quantum heat transfer in a driven nonequilibrium spin-boson model, we develop a generalized nonequilibrium polaron-transformed Redfield equation with an auxiliary counting field. This enables us to study the impact of qubit-bath coupling ranging from weak to strong regimes. Without external modulations, we observe maximal values of both steady-state heat flux and noise power in moderate coupling regimes, below which we find that these two transport quantities are enhanced by the finite-qubit-energy bias. With external modulations, the geometric-phase-induced heat flux shows a monotonic decrease upon increasing the qubit-bath coupling at zero qubit energy bias (without bias). While under the finite-qubit-energy bias (with bias), the geometric-phase-induced heat flux exhibits an interesting reversal behavior in the strong coupling regime. Our results unify the seemingly contradictory results in weak and strong qubit-bath coupling regimes and provide detailed dissections for the quantum fluctuation of nonequilibrium heat transfer.

The thermodynamic uncertainty relation, quantifying a trade-off among average current, the associated fluctuation (precision), and entropy production (cost), has been formulated at nonequilibrium steady state in various stochastic systems. Herein, we study the thermodynamic uncertainty relation in generic thermoelectric heat engines under periodic control protocols, by uncovering the underlying Berry-phase-like contribution. We show that our thermodynamic uncertainty relation breaks the seminal steady-state results, originating from the nonvanishing geometric effect. Furthermore, by deriving the consequent trade-off relation binding efficiency, power, and constancy, we prove that the periodically driven thermoelectric heat engines can generally outperform the steady-state analogies. The general bounds are illustrated by an analytically solvable two-terminal single quantum dot heat engine under the periodic modulation. Our work provides a geometric framework in bounding and optimizing a wide range of periodically driven thermoelectric thermal machines.

The second law of thermodynamics dictates that heat simultaneously flows from the hot to cold bath on average. To go beyond this picture, a range of works in the past decade show that, other than the average dynamical heat flux determined by instantaneous thermal bias, a non-trivial flux contribution of intrinsic geometric origin is generally present in temporally driven systems. This additional heat flux provides a free lunch for the pumped heat and could even drive heat against the bias. We review here the emergence and development of this so called “geometric heat pump”, originating from the topological geometric phase effect, and cover various quantum and classical transport systems with different internal dynamics. The generalization from the adiabatic to the non-adiabatic regime and the application of control theory are also discussed. Then, we briefly discuss the symmetry restriction on the heat pump effect, such as duality, supersymmetry and time-reversal symmetry. Finally, we examine open problems concerning the geometric heat pump process and elucidate their prospective significance in devising thermal machines with high performance.

We investigate the nonequilibrium quantum heat transfer in a quantum thermal transistor, constructed by a triangle-coupled spin-boson system in a three-terminal setup. By exploiting the nonequilibrium noninteracting blip approximation approach combined with full counting statistics, we obtain the steady-state thermal transport, such as heat currents. We identify the giant heat amplification feature in a strong coupling regime, which results from the negative differential thermal conductance with respect to the gate temperature. Analysis shows that the strong coupling between the gate qubit and corresponding gate thermal bath plays the crucial role in exhibiting these far-from-equilibrium features. These results would have potential implications in designing efficient quantum thermal transistors in the future.

Including the phonon-assisted inelastic process in thermoelectric devices makes it possible to enhance the performance of nonequilibrium work extraction. In this work, we demonstrate that inelastic phonon-thermoelectric devices have a fertile functionality diagram, where particle current and phononic heat currents are coupled and fueled by the chemical potential difference. Such devices can simultaneously perform multiple tasks, e.g., heat engines, refrigerators, and heat pumps. Guided by the entropy production, we mainly study the efficiencies and coefficients of performance of multitask quantum thermal machines, where the roles of the inelastic scattering process and multiple biases in multiterminal setups are emphasized. Specifically, in a three-terminal double-quantum-dot setup with a tunable gate, we show that it efficiently performs two useful tasks due to the phonon-assisted inelastic process. For the four-terminal four-quantum-dot thermoelectric setup, we find that additional thermodynamic affinity furnishes the system with both enriched functionality and enhanced efficiency. Our work provides insights into optimizing phonon-thermoelectric devices.

Thermal rectification and heat amplification are investigated in a nonequilibrium V-type three-level system with quantum interference. By applying the Redfield master equation combined with full counting statistics, we analyze the steady-state heat transport. The noise-induced interference is found to be able to rectify the heat current, which paves a new way to design quantum thermal rectifier. Within the three-reservoir setup, the heat amplification is clearly identified far from equilibrium, which is in absence of the negative differential thermal conductance.