In this work, a series of Cu2O/S (S = α-MnO2, CeO2, ZSM-5, and Fe2O3) supported catalysts with a Cu2O loading amount of 15% were prepared by the facile liquid-phase reduction deposition–precipitation strategy and investigated as CO oxidation catalysts. It was found that the Cu2O/α-MnO2 catalyst exhibits the best catalytic activity for CO oxidation. Additionally, a series of Cu2O-CuO/α-MnO2 heterojunctions with varied proportion of Cu+/Cu2+ were synthesized by further calcining the pristine Cu2O/α-MnO2 catalyst. The ratio of the Cu+/Cu2+ could be facilely regulated by controlling the calcination temperature. It is worth noting that the Cu2O-CuO/α-MnO2-260 catalyst displays the best catalytic performance. Moreover, the kinetic studies manifest that the apparent activation energy could be greatly reduced owing to the excellent redox property and the Cu2O-CuO interface effect. Therefore, the Cu2O-CuO heterojunction catalysts supported on α-MnO2 nanotubes are believed to be the potential catalyst candidates for CO oxidation with advanced performance.
Magnetic polymers are often used as loading materials for ionic liquids because of their excellent magnetic separation properties. In this study, a novel imidazolium-based ionic liquid-modified magnetic polymer was synthesized by suspension polymerization and grafting, denoted as γ-Fe2O3@GMA@IM, and this magnetic polymer was used for the adsorption of the acid dye FCF. The magnetic polymer was characterized by SEM, FTIR, XRD, VSM and TGA. These techniques were used to reveal the overall physical properties of magnetic polymers, including the presence of morphology, functional groups, crystalline properties, magnetism and thermal stability. Studies have shown that γ-Fe2O3@GMA@IM can adsorb FCF in a wide pH range (2–10), with a maximum adsorption capacity of 445 mg/g. The adsorption data were more in line with the pseudo-second-order kinetic model and the Freundlich isotherm. In order to investigate its reusability, this study used 10% NaCl as the desorption solution, and carried out five batches of adsorption–desorption cycles. After five cycles, the adsorption effect was maintained at 98.3%, which showed a good recycling performance.