It is widely accepted that moving from a linear to circular economy for plastics will be beneficial to reduce plastic pollution in our environment and to prevent loss of material value. However, challenges within the sorting of plastic waste often lead to contaminated waste streams that can devalue recyclates and hinder reprocessing. Therefore, the improvement of the sorting of plastic waste can lead to dramatic improvements in recyclate quality and enable circularity for plastics. Here, we discuss current sorting methods for plastic waste and review labeling techniques to enable enhanced sorting of plastic recyclates. Photoluminescent-based labeling is discussed in detail, including UV-vis organic and inorganic photoluminescent markers, infrared up-conversion, and X-ray fluorescent markers. Methods of incorporating labels within packaging, such as extrusion, surface coatings, and incorporation within external labels are also discussed. Additionally, we highlight some practical models for implementing some of the sorting techniques and provide an outlook for this growing field of research.

The production of well‐defined and reproducible polymeric nanoparticles (NPs), in terms of size and stability in biological environments, is undoubtedly a fundamental challenge in the formulation of novel and more effective nanomedicines. The adoption of PEGylated lactide (LA) block copolymers as biodegradable and biocompatible nanocarriers at different clinical stages has rendered these materials an attractive polymeric platform to be exploited and their formulation is further understood. In the present work, we synthesized a library of linear polyethylene glycol‐poly(D,L‐lactide) block copolymers with different lengths of LA (15, 25, 50, and 100 LA units) via simple and metal‐free ring‐opening polymerization, in order to alter the amphiphilic balance of the different macromolecules. The produced polymers were formulated into NPs while varying a series of key parameters in the solvent displacement process, including solvent:nonsolvent ratios and the nature of the two media, and the effect on size and stability was assessed. In addition, stability to protein–NPs interaction and aggregation was studied, highlighting the different NP final properties according to the nature of the amphiphilic balance and nanoformulation conditions. Therefore, we have illustrated a systematic and methodological process to optimize a series of NPs parameters balancing particle size, size distribution, surface charge, and stability to guide future works in the nanoformulation field. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1801–1810

Metal oxide microparticles with well-defined internal mesostructures are promising materials for a variety of different applications, but practical routes to such materials that allow the constituent structural length scales to be precisely tuned have thus far been difficult to realize. Herein, we describe a novel platform methodology that utilizes self-assembled block copolymer (BCP) microparticles synthesized by dispersion polymerization in supercritical CO2 (scCO2) as universal structure directing agents for both hydrolytic and non-hydrolytic sol-gel routes to metal oxides. Spherically structured poly(methyl methacrylate-block-4-vinyl pyridine) (PMMA-b-P4VP) BCP microparticles are translated into a series of the corresponding organic/inorganic composites and pure inorganic derivatives with a high degree of fidelity for the metal oxides TiO2 and LiFePO4. The final products are comprised of particles close to 1 μm in size with a highly ordered internal morphology of interconnected spheres between 20 – 40 nm in size. Furthermore, our approach is readily scalable, enabling grams of pure or carbon coated TiO2 and LiFePO4, respectively, to be fabricated in a facile two step route involving ambient temperature mixing and drying stages. Given that both length scales within these BCP microparticles can be controlled independently by minor variations in the reagent quantities used, the present general strategy could represent a milestone in the design and synthesis of hierarchical metal oxides with completely tunable dimensions.

Reuse of plastic packaging for food is a promising route to reduce the environmental burdens, but presents particular challenges due to the need to avoid cross-contamination of contents. This study investigates the challenges associated with cleaning and assessing existing recycled PET (rPET) food-to-go (FTG) pack forms and provides recommendations to enable a shift towards reusable food packaging systems. Pack forms were fouled under controlled conditions and washed in accordance published guidelines. Three fouling media were selected to represent food residue typically found in FTG packs. Investigated parameters included fouling type and quality, wash and rinse times, and detergent dosage. Cleanliness was assessed using adenosine triphosphate (ATP) swabbing and the effect on the material properties was studied via tensile testing, IR spectroscopy and differential scanning calorimetry. The results demonstrate that cleaning effectiveness is dependent on the quantity of fouling, the duration of the wash cycle and the dosing of detergent indicating the potential to optimise parameters for different fouling conditions. It is also concluded that ATP testing is an inappropriate cleanliness assessment method for food packaging due to many opportunities for it to produce false negative readings, its high cost, and slow response. The rPET material properties remained largely unchanged apart from a slight increase in stiffness, however packaging suffered significant deformation.

We report the synthesis of phase separated PMMA-b-PS-b-P4VP microparticlesviaRAFT-mediated dispersion polymerisation in scCO₂and their use as a structure-directing agent for the fabrication of TiO₂microparticles for photocatalysis.