This study investigates a new type of high-performance coated sand as a petroleum fracturing proppant material. Modified quartz sand was coated with a layer of low-density resin to reduce the overall density of the proppant, thereby improving the suspension of the proppant in the fracturing fluid. Resins play an important role in the preparation of coated sand fracturing proppants. The mechanism of sand formation was studied by examining the phase composition and microstructure of the coated sand proppant. The results demonstrate that when the polyimide resin content is 6% and the curing temperature is 180 °C, the proppant exhibited the best performance with an apparent density of 1.592 g/cm³ and a breakage ratio of only 3.22% under 55.2 MPa. Compared with the widely used epoxy resin-coated support agent and phenolic resin-coated support agent in the early stage, their crushing rate decreased by 5% and their acid solubility decreased by 2%. Hence, this study is worthy of attention.

Oil and gas resources are becoming increasingly difficult to extract owing to long-term exploitation. Therefore, hydraulic pressure technologies, such as fracturing proppants, are needed to stimulate production. In this study, the strength and corrosion resistance of quartz were increased by modifying quartz sand and preparing high-performance coated-sand-based oil-fracturing proppants. Although many resins play crucial roles in the process of preparing fracturing proppants, their performances differ considerably. Chemical structural compositions and microstructures were investigated through infrared spectroscopy and scanning electron microscopy. The modification mechanism of quartz sand and the bonding mechanism between quartz sand and different types of resin proppants were analyzed by systematically investigating the flexural strength, corrosion resistance of the proppants as a function of resin contents, and curing temperature. The results show that the performance of the coated proppants is superior to those of conventional quartz sand and ceramic proppants. The flexural strength of modified quartz sand improved by 5.3%. The best performance was obtained using an 8% polyimide resin film and a curing temperature of 180 °C, achieving a coated sand proppant with a breakage ratio of 2.89% under 55.2 MPa.

Natural hydraulic lime (NHL) is a cementitious material widely used in the restoration of stone cultural relics and maintenance of historic buildings, the practical use of which is mainly hindered by its poor fluidity. Due to the multilayer (double-layer) adsorption that isobutylene–maleic anhydride (IBMA) has on the surface of NHL, the effects that IBMA copolymer have on the fluidity and hydration of NHL were thus investigated. Moreover, the yield stress and plastic viscosity of NHL pastes were found to be reduced significantly by the incorporation of IBMA. Combined with the effects of electrostatic repulsion and steric hindrance, the flocculated structures in NHL pastes were gradually dismantled, releasing the trapped water and leading to a significant enhancement in the fluidity of NHL. IBMA was found to postpone the early hydration of NHL. In particular, it showed that adding specific content of IBMA can significantly improve the early strength of NHL.