The six-degree-of-freedom (6 DOF) motion of the mother ship, especially the heave motion, brings difficulties to offshore operations and even causes safety accidents. To ensure the reliability of the launch and recovery system when the active heave compensation (AHC) function works, its dynamic characteristics are analyzed. Firstly, the dynamic model of the launch and recovery system with a rigid rope is constructed, and the mathematical simulation of the launch and recovery system without the AHC function under the excitation of irregular waves is completed. Secondly, a flexible rope based on the finite element method is established, and the dynamic responses of the launch and recovery system with AHC function under different conditions are compared with those without AHC function. The simulation results demonstrate that the dynamic responses of the system are related to the load, the underwater penetration, and the sea condition. In detail, the increase of the load leads to an increase in the dynamic response of the system. In essence, the underwater penetration affects the dynamic response of the system by affecting the activity of load acceleration. Therefore, a short rope is preferred in the maritime operations. Moreover, the harsh sea condition usually causes an undesirable effect of AHC function. In summary, the overall work is conductive to the modeling of the launch and recovery system, as well as the development of AHC technology so as to improve the quality of offshore operations in the future.
The electrocaloric effect of ferroelectrics is promising for new solid-state refrigeration. However, the current research on the electrocaloric effect of bulk ferroelectrics mainly focuses on (001) orientation. Thus, we studied the electrocaloric effect of BaZr0.15Ti0.85O3 single crystals with different orientations through the nonlinear thermodynamic approach and entropy analysis. The results show that the dipolar entropy of (111)-oriented BaZr0.15Ti0.85O3 single crystals exhibits a greater change after applying an external electric field, compared with (001)- and (110)-orientations, and the (001)-oriented electrocaloric responses are consistent with experimental observations. The (111)-oriented BaZr0.15Ti0.85O3 single crystals have a more significant electrocaloric response, resulting in a broader work temperature range with a large electrocaloric effect. These insights offer an alternative way to enhance the electrocaloric response of ferroelectric single crystals.
Hierarchical PbS powders doped with different contents of Bi2S3 and Cu2S were synthesized using the hydrothermal method. Subsequently, the powders were subjected to spark plasma sintering (SPS) for consolidation into bulk ceramics. X-ray photoelectron spectroscopy results showed that Bi2S3 and Cu2S were doped into PbS successfully. The effect of doping with different Bi2S3 and Cu2S contents on thermoelectric performance was investigated systematically. The results showed that pure PbS was an n-type semiconductor, and Bi2S3 doping or Bi2S3-Cu2S co-doping could decrease the thermal conductivity of PbS effectively. PbS doped with 1% Bi2S3 exhibited a moderate Seebeck coefficient, high electric conductivity, and low thermal conductivity simultaneously, thus attaining a maximum figure of merit ZT of 0.55 at 773 K. PbS doped with 1% Bi2S3-1% Cu2S exhibited an enhanced power factor and reduced thermal conductivity at an elevated temperature; the maximum ZT value obtained at 773 K was 0.83, which is more than twice that of pure PbS at 758 K (0.29), as a result.
Dendrite growth has been the main trouble preventing the practical application of Li metal anodes. Herein, we present how an Fe3O4-PVDF composite network prepared by using electrospinning has been designed to protect lithium metal anodes effectively. In the symmetrical cells test, the cell with the Fe3O4-PVDF composite network maintains good cycle performance after 600 h (500 cycles) at a current density of 1 mA cm−2 and a plating/stripping capacity of 1 mAh cm−2. The bulky Li dendrite is suppressed and a uniform Li deposition remains after long cycling. The characteristics of this engineered separator are further demonstrated in Li-S full cells with a good cycle performance (capacity of 419 mAh g−1 after 300 cycles at 0.5 C). This work provides a new idea for the protection of lithium metal anodes.