Herein, three types of graphene oxides (GOs, GO-M1, GO-M2 and GO-M3) have been successfully prepared from graphite by three different methods and utilized for the removal of Cr(VI) from aqueous solutions. Further, the effects of initial concentration and pH, adsorbent dosage, contact time and temperature on the adsorption performance of GOs were investigated by batch adsorption experiments. Furthermore, the adsorption mechanisms for Cr(VI) adsorption by GOs are mainly the redox reaction and electrostatic attraction, while there are also pore filling, ion exchange and complexation involved in these adsorption processes. The adsorption kinetic and isotherm data indicate that these adsorption processes of GOs on Cr(VI) are dominantly monolayer chemisorption and equilibrium can be reached in 30 min. The saturation adsorption capacities (Q_m, 298.15 K) of GO-M1, GO-M2 and GO-M3 for Cr(VI) are estimated to be 3.5412 mg⋅g⁻¹, 2.3631 mg⋅g⁻¹ and 7.0358 mg⋅g⁻¹, respectively. Moreover, the adsorption thermodynamic study showed that these adsorption processes of Cr(VI) by the three types of GOs at 298.15 K to 323.15 K are endothermic, entropy-driven and thermodynamically spontaneous and feasible. Overall, these findings provided vital insights into the mechanism and application of Cr(VI) removal by GOs.

Advanced oxidation processes (AOPs) demonstrate great micropollutant degradation efficiency. In this study, CuFe₂O₄ was successfully used to activate peracetic acid (PAA) to remove Rhodamine B. Acetyl(per)oxyl radicals were the dominant species in this novel system. The addition of 2,4-hexadiene (2,4-HD) and Methanol (MeOH) significantly inhibited the degradation efficiency of Rhodamine B. The ≡Cu²⁺/≡Cu⁺ redox cycle dominated PAA activation, thereby producing organic radicals (R-O˙) including CH₃C(O)O˙ and CH₃C(O)OO˙, which accounted for the degradation of Rhodamine B. Increasing either the concentration of CuFe₂O₄ (0–100 mg/L) or PAA (10–100 mg/L) promoted the removal efficiency of this potent system. In addition, weakly acid to weakly alkali pH conditions (6–8) were suitable for pollutant removal. The addition of Humid acid (HA), HCO₃⁻, and a small amount of Cl⁻ (10–100 mmol·L⁻¹) slightly inhibited the degradation of Rhodamine B. However, degradation was accelerated by the inclusion of high concentrations (200 mmol·L⁻¹) of Cl⁻. After four iterations of catalyst recycling, the degradation efficiency remained stable and no additional functional group characteristic peaks were observed. Taking into consideration the reaction conditions, interfering substances, system stability, and pollutant-removal efficiency, the CuFe₂O₄/PAA system demonstrated great potential for the degradation of Rhodamine B.