Geopolymer recycled aggregate concrete (GPRAC) is a new type of green material with broad application prospects by replacing ordinary Portland cement with geopolymer and natural aggregates with recycled aggregates. This paper summarizes the research about the mechanical properties, durability, and microscopic aspects of GPRAC. The reviewed contents include compressive strength, elastic modulus, flexural strength, splitting tensile strength, freeze–thaw resistance, abrasion resistance, sulfate corrosion resistance, and chloride penetration resistance. It is found that GPRAC can be made to work better by changing the curing temperature, using different precursor materials, adding fibers and nanoparticles, and setting optimal mix ratios. Among them, using multiple precursor materials in synergy tended to show better performance compared to a single precursor material. In addition, using modified recycled aggregates, the porosity and water absorption decreased by 18.97% and 25.33%, respectively, and the apparent density was similar to that of natural aggregates. The current results show that the performance of GPRAC can meet engineering requirements. In addition, compared with traditional concrete, the use of GPRAC can effectively reduce carbon emissions, energy loss, and environmental pollution, which is in line with the concept of green and low-carbon development in modern society. In general, GPRAC has good prospects and development space. This paper reviews the effects of factors such as recycled aggregate admixture and curing temperature on the performance of GPRAC, which helps to optimize the ratio design and curing conditions, as well as provide guidance for the application of recycled aggregate in geopolymer concrete, and also supply theoretical support for the subsequent application of GPRAC in practical engineering.

Geopolymer composites can be used as a proper substitute for ordinary Portland cement, which can reduce carbon dioxide (CO₂) emissions and make rational use of industrial waste. In this study, an investigation of the workability and compressive strength of geopolymer composites was carried out through a series of experiments, such as slump flow test, consistency meter test and compressive strength test, to clarify the interaction mechanism among superplasticizer (SP), polyvinyl alcohol (PVA) fiber, Nano-SiO₂ (NS) and geopolymer composites, thereby improving the properties of engineered composites. The results showed that with the increase in PVA fiber content, the flowability of geopolymer composites decreased, while the thixotropy increased. With the increase in the NS content, the flowability of geopolymer composites first increased and then decreased, reaching its best at 1.0%, while the thixotropy was the opposite. With the increase in the SP content, the flowability of geopolymer composites increased, while the thixotropy decreased. A significant correlation between thixotropy and flowability of geopolymer composites was found (R² > 0.85). In addition, the incorporation of single PVA fiber or NS significantly improved the compressive strength of geopolymer composites. Specifically, the compressive strength of geopolymer composites with 0.8% content PVA fiber (60.3 MPa) was 33.4% higher than that without PVA fiber (45.2 MPa), and the compressive strength of geopolymer composites with 1.5% content NS (52.6 MPa) was 16.4% higher than that without NS (45.2 MPa). Considering the synergistic effect, it is found that the compressive strength of geopolymer composites (58.5–63.3 MPa) was significantly higher than that without PVA fiber (45.2–52.6 MPa). However, the flowability and compressive strength of geopolymer composites were only slightly improved compared to that without NS. With the increase in the SP content, the compressive strength of geopolymer composites showed a trend of a slight decrease on the whole. Consequently, the results of this study may be useful for further research in the field of repair and prevention of the delamination of composite structures.

Cement-based composites’, as the most widely used building material, macroscopic performance significantly influences the safety of engineering structures. Meanwhile, the macroscopic properties of cement-based composites are tightly related to their microscopic structure. The complexity of cement-based composites’ microscopic structure is challenging to describe geometrically, so fractal theory is extensively applied to quantify the microscopic structure of cement-based composites. However, existing studies have not clearly defined the quantification methods for various microscopic structures in CCs, nor have they provided a comprehensive evaluation of the correlation between the fractal dimensions of different microscopic structures and macroscopic performance. So, this study categorizes the commonly used testing methods in fractal theory into three categories: particle distribution (laser granulometry, etc.), pore structure (mercury intrusion porosity, etc.), and fracture (computed tomography, etc.). It systematically establishes a detailed process for the application of testing methods, the processing of test results, model building, and fractal dimension calculation. The applicability of different fractal dimension calculation models and the range of the same fractal dimension established by different models are compared and discussed, and the advantages and disadvantages of different models are analyzed. Finally, the research delves into an in-depth analysis of the relationship between the fractal dimension of cement-based composites’ microscopic structure and its macroscopic properties, such as compressive strength, corrosion resistance, impermeability, and high-temperature resistance. The principle that affects the positive and negative correlation between fractal dimension and macroscopic performance is discussed and revealed in this study. The comprehensive review in this paper provides scholars with methods and models for quantitative research on the microscopic structural parameters of cement-based composites and offers a pathway for the non-destructive assessment of the macroscopic performance of cement-based composites.