Zn-based batteries have been identified as promising candidates for flexible and wearable batteries because of their merits of intrinsic safety, eco-efficiency, high capacity and cost-effectiveness. Polymer electrolytes, which feature high solubility of zinc salts and softness, are especially advantageous for flexible Zn-based batteries. However, many technical issues still need to be addressed in Zn-based batteries with polymer electrolytes for their future application in wearable electronics. Recent progress in advanced flexible Zn-based batteries based on polymer electrolytes, including functional hydrogel electrolytes and solid polymer electrolytes, as well as the interfacial interactions between polymer electrolytes and electrodes in battery devices, is comprehensively reviewed and discussed with a focus on their fabrication, performance validation, and intriguing affiliated functions. Moreover, relevant challenges and some potential strategies are also summarized and analyzed to help inform the future direction of polymer-electrolyte-based flexible Zn-based batteries with high practicability.

Porous materials as electrode materials have demonstrated numerous benefits for high-performance Zn-ion batteries in recent years. In brief, porous materials as positive electrodes provide distinctive features such as faster electron transport, shorter ion diffusion distance, and richer electroactive reaction sites, which improve the kinetics of positive electrode reactions and achieve higher rate capacity. On the other hand, the porous structures as negative electrodes also exhibit electrochemical properties possessing higher surface area and reducing local current density, which favors the uniform Zn deposition and restrains the dendrite formation. In view of their advantages, porous electrode materials for ZIB are expected to be extensively applied in electric and hybrid electric vehicles and portable electronic devices. In this review, we highlight the methods of synthesizing porous electrode materials and discuss the mechanism of action of porous structures as electrodes on their electrochemical properties. At the end of this review, the perspectives on the future development of porous materials in the field of electrochemical energy storage are also discussed.

With the advantages of benign mechanical property, electrochemical stability, and low cost, graphite fibers (GFs) have been widely used as electrodes for vanadium redox flow batteries (VRFBs). However, GFs usually possess inferior electrochemical activity and ion diffusion kinetics for electrode reaction, vastly limiting their application in VRFBs. Here, a 3D carbon nanonetwork coated GFs with multi-heteroatom doping was constructed for application in VRFBs via low temperature polymerization between linear polymer monomer and phytic acid, and subsequent carbonization (900 °C) on the GFs (GF@PCNs-900). Benefiting from the 3D structural features and multi-heteroatom doping (O, N and P), the composite electrode displayed sufficient diffusion of vanadium ions, rapid electron conduction, and highly enhanced electrochemical activity of reactive site on the electrodes. As a result, the GF@PCNs-900 delivered a high discharge capacity of 21 Ah L⁻¹ and energy efficiency of above 70% with extraordinary stability during 200 cycles at 200 mA cm⁻². Even at a huge current density of 400 mA cm⁻², the GF@PCNs-900 still maintained a discharge capacity of 5.0 Ah L⁻¹, indicating an excellent rate of performance for VRFBs. Such design strategy opens up a clear view for further development of energy storage field.