We demonstrate highly flexible and efficient organic light-emitting devices (OLEDs) using an ultra-smooth NAN anode. A template-stripping process was employed to create an ultra-smooth NAN anode on a photopolymer substrate. The flexible OLEDs obtained by this method maintained good electroluminescent properties and mechanical stability after bending. The efficiency of the flexible OLEDs was improved by 30.6% compared with conventional OLEDs deposited on PET/ITO substrate due to the enhanced hole injection from the ultra-smooth anode.

A substrate with microstructure can increase the light extraction efficiency of OLEDs. However, the present preparation methods for micro- and nanostructures are not suited for broad-area manufacturing. In this research, we suggested an electrochemical etching approach to patterning Si substrates and effectively generated a vast area of micro-/nanostructures on the surface of Si. We created OLEDs using this patterned substrate. It was discovered through this study that when the current density is 100 mA/cm², the brightness increases by 1.67 times and the efficiency increases by 1.43 times, over a planar equivalent. In the future, this electrochemical etching process for patterned silicon substrates might give rise to a new approach to the large-scale manufacture of microstructured silicon substrates.