The provenance study of the sediments from Qinghai Lake is of great significance for the understanding of geological and climatic evolution processes of the Tibet Plateau on the one hand and for evaluating the controlling factors of the sediment components on the other hand. The samples were collected from five rivers, foreshore, beach, beach bar, and aeolian sand dune in the Qinghai Lake. The bulk geochemical composition, petrography, and mineralogy features of the samples are analyzed. The results show that: 1) Qinghai Lake sediments experienced low-intensity chemical weathering from the source areas to the deposition sites and were affected by some recycled detrital materials and 2) the source rocks for the sediments include felsic rocks (granite, granodiorite, and felsic volcanic rocks), carbonate, metamorphic rocks (marble and meta-volcanic rocks), and clastic rocks with the felsic source rocks to have the most important impact on the chemical compositions of the sediments. The geochemical indicator of Al2O3/TiO2 reflects that the provenance of fine-grained sediments from the center of Qinghai Lake is more mafic than the coarse-grained sediments from the margin of the Qinghai Lake, suggesting that the hydraulic sorting of grain size probably plays an important role in the geochemical compositions of the sediments. The mafic elements were probably preferentially enriched in muds.
The Chang 7 member of the Upper Triassic Yanchang Formation in the Ordos Basin is considered to hold the main source rocks for conventional and unconventional oil and gas. The lamination or lithology alteration in vertical and lateral directions, even over a short distance, is a common feature in lacustrine source rocks. The differences in the geochemical characteristics of black shales, dark mudstones and interbedded sandstones have been scarcely reported, and their influences on the petroleum generation potential and shale oil potential are not clear. To this end, 22 core samples were collected from the Lower and Middle Chang 7 (C7-3 and C7-2) members of the Triassic from well CYX in the Qingcheng area. By conducting a series of geochemical analyses including TOC, Rock-Eval pyrolysis yields, bitumen extraction and quantification, and the separation and quantification of saturates, aromatics, resins and asphaltenes, along with biomarker analyses, several results were found. Firstly, the C7-3 and C7-2 source rocks are thermally mature and have entered into the stage of hydrocarbon generation. The C7-3 and C7-2 source rocks have a good to very good hydrocarbon generation potential especially the C7-3 black shales. Secondly, terrigenous source input is more abundant in C7-2, whereas the source input of phytoplankton, algae or microbial lipids is more abundant in C7-3. Moreover, a high TOC content basically corresponds to low wax indexes, terrigenous/aquatic ratios (TARs), and Pr/nC17 and Ph/nC18 ratios and high C27/C29 regular sterane ratios, which suggests that the source input of phytoplankton, algae or microbial lipids is favorable for OM accumulation. Third, analyses of the molecular composition of saturated fractions in shales and interbedded sandstones and the production index demonstrate the migration of petroleum from organic-rich source rocks to their organic-lean counterparts. The C7-2 dark mudstones could be considered as a potential “sweet spot” since their oil saturation index (OSI) was the highest among all the studied samples and they are more enriched in light aliphatic fractions.
The concentric layers of ooids from the modern environment are mostly aragonite and those from the ancient are mostly calcite and Mg-calcite. Dolomitic ooids are rare and are usually formed via the replacement of aragonite or calcite. Here, dolomitic ooids were found in the Pliocene Shizigou Formation in the Qaidam Basin, Northern Tibet Plateau. This paper focuses on whether the dolomitic ooids is a primary precipitate. Optical microscope and scanning electron microscope observation, combined with X-ray diffraction and cathodoluminescence analyses, indicate that the primary mineral of the ooid cortices is poorly ordered dolomite. Extracellular polymeric substances and pyrite were found in the ooids, indicating that the microbe participation was involved in the formation of the ooids. Firstly, the ooids grow on the offshore lake floor. Due to the involvement of sulfate-reducing bacteria and dissolved silica, the nanominerals were precipitated on extracellular polymeric substances. Then, the ooids were transported to strong hydrodynamic surf zones, where the random nanominerals were abraded to form flattened plates as a new polished layer. In addition, a comparison between the carbon and oxygen isotopic compositions and minerals of ooids from different periods indicate that the Pliocene lakes had a lower salinity and were more humid than Pleistocene lakes. Therefore, ooids may be an effective proxy for reflecting the climatic change and uplift history of the Tibet Plateau.
Ooids are coated carbonate grains, which exist in shallow water marine and lacustrine environments. There is an ongoing debate about whether the origin of ooids is inorganic or organic. Qinghai Lake is the largest inland lake in China, and ooids are seen on the lake shore. This paper focuses on whether environmental energy has an impact on the growth and size of ooids. Through hydrochemical analysis, thin section observation, and scanning electron microscope, the carbonate coats of beach sands from Qinghai Lake were studied. The research shows that the carbonate-coated grain content from the different shores of the lake present variations. The hydrodynamics and particularly the waves seem to control the distribution of carbonate coats in the lake shore, not the hydrochemical condition. In addition, the integrity and thickness of carbonate coats from the shores with a strong hydrodynamic force are high and thick, respectively. The carbonate coats are often observed on medium-grained sands, and the maximum carbonate-coated grain occurred under the strongest waves, indicating that ooids can be produced only when hydrodynamic force and particle size are well matched. Bacteria or extracellular polymeric substances are not observed within the ooid cortices by scanning electron microscopy. So, bacteria may not be a major factor in the formation and growth of ooids, but hydrodynamic forces appear to play a great role in carbonate grain coat distribution, integrity, thickness, and ooid grain size.