Groundwater is undoubtedly important for water supplies and eco-environment protection, especially for arid and semi-arid regions. Analyzing the characteristics and evolution of groundwater is significant for the rational management of groundwater resources. This study investigated the hydrogeochemical characteristics and evolutions of groundwater in the Delingha area, northeast of the Qaidam Basin, northwest China, with a total of 123 water samples, including 105 unconfined groundwater samples, 12 confined groundwater samples, and 6 surface water samples. Hydrochemical results showed that the unconfined and confined groundwater presented diversity in ion concentration. Total Dissolved Solids (TDS) of the unconfined groundwater increased from 146.5 to 8954 mg/L along the groundwater flow direction. The groundwater hydrochemical types were HCO3-Ca·Mg and HCO3·SO4-Ca·Mg in the mountain front area, SO4·HCO3-Ca·Mg and SO4·Cl-Ca·Mg types in the alluvial-lacustrine plain, and Cl·SO4-Na and Cl-Na types in the lacustrine plain. The saturation index showed that parts of the groundwater samples were supersaturated with carbonate minerals (calcite and dolomite); however, all the samples were undersaturated with evaporite minerals (halite and gypsum). Groundwater chemical evolution is mainly controlled by evaporite and carbonate mineral dissolutions, aluminosilicates weathering, and cation exchange.
Groundwater is a critical water resource for human survival and economic development in arid and semi-arid areas. It is crucial to understand the groundwater circulation and hydrochemical evolution for sustainable management and utilization of groundwater resources in those areas. To this end, an investigation of the hydrochemical characteristics of surface water and groundwater was conducted in Nomhon, an arid area located in the Qaidam Basin, northwest China, by using hydrochemical (major and trace elements) and stable isotopes (δD and δ18O) approaches. Stable isotopes and ion ratios were analyzed to determine the recharge sources, hydrochemistry characteristics, and major hydrogeochemical processes. Meanwhile, inverse geochemistry modeling was applied to quantitatively determine the mass transfer of hydrogeochemical processes. The results showed that groundwater in the study area is mainly recharged by atmospheric precipitation in mountainous areas, and the groundwater in the center of basin might originate from ancient water in cold and humid environments. Along the groundwater flow path, the TDS of groundwater increased gradually from fresh to salty (ranging from 462.50 to 19,604.40 mg/L), and the hydrochemical type changed from Cl·HCO3–Na·Mg·Ca to Cl–Na. Groundwater chemical composition and mass balance modeling results indicated that from alluvial fan to lacustrine plain, the main hydrogeochemical processes changed from the dissolution of halite and albite and the precipitation of dolomite and kaolinite to the dissolution of halite and gypsum, precipitation of calcite, redox (SO42− reduction), and cation exchange. This study would be helpful for water resources management in this area and other similar areas.
Groundwater sustainability has become a critical issue for Zhanjiang (China) because of serious groundwater level drawdown induced by overexploitation of its coastal multilayered aquifer system. It is necessary to understand the origins, material sources, hydrochemical processes, and dynamics of the coastal groundwater in Zhanjiang to support its sustainable management. To this end, an integrated analysis of hydrochemical and isotopic data of 95 groundwater samples was conducted. Hydrochemical analysis shows that coastal groundwater is fresh; however, relatively high levels of Cl−, Mg2+, and total dissolved solid (TDS) imply slight seawater mixing with coastal unconfined groundwater. Stable isotopes (δ18O andδ2H) values reveal the recharge sources of groundwater in the multilayered aquifer system. The unconfined groundwater originates from local modern precipitation; the confined groundwater in mainland originates from modern precipitation in northwestern mountain area, and the confined groundwater in Donghai and Leizhou is sourced from rainfall recharge during an older period with a colder climate. Ionic relations demonstrate that silicate weathering, carbonate dissolutions, and cation exchange are the primary processes controlling the groundwater chemical composition. Declining trends of groundwater level and increasing trends of TDS of the confined groundwater in islands reveal the landward extending tendency of the freshwater-seawater mixing zone.
Although different methods have been employed to study the earthquake‐induced changes in aquifer permeability (e.g., tidal/barometric pressure response and analytical models), identification of the mechanism is usually hindered by the limitation of application conditions or multiplicity of solutions. A numerical simulation that couples flow and heat transport is developed in the present study to explain the coseismic responses that followed two large earthquakes (Mw 7.0 Lijiang earthquake on 3 February 1996 and Mw 9.1 Sumatra earthquake on 26 December 2004) at Banglazhang #1 hot spring, China. The results show that decreased spring discharge and temperature are attributable to earthquake‐induced permeability decrease, which can be related to the blocking of narrow fracture apertures. Analysis of the model revealed that seismic waves may have caused heterogeneous changes in permeability within the fault zone hydrothermal system, which led to nonsynchronous changes in spring flow and temperature. Our study contributes to an enhanced understanding of the impact of the evolution of earthquake‐induced permeability in hydrothermal systems.