Rajeev Chikate

Prof. Rajeev Chikate

orcid

Research Focus & Metrics

Academic Career Length

37Years (1990-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 February 1993 in Coordination Chemistry Reviews
Verified
Journal Article
Closed access
DWDouglas X. West
Douglas X. West
ALAnthony E. Liberta
Anthony E. Liberta
SPSubhash B. Padhye
Subhash B. Padhye
RCRajeev Chikate
Rajeev Chikate
PSPramila B. Sonawane
Pramila B. Sonawane
RYRatnamala G. Yerande
Ratnamala G. Yerande

1 March 2008 in Applied Catalysis B: Environment and Energy
Verified
Journal Article
Closed access
ABAlok D. Bokare
Alok D. Bokare
RCRajeev Chikate
Rajeev Chikate
CRChandrashekhar V. Rode
Chandrashekhar V. Rode
KPKishore M. Paknikar
Kishore M. Paknikar

22 September 2007 in Environmental Science & Technology
Verified
Journal Article
Closed access
ABAlok D. Bokare
Alok D. Bokare
RCRajeev Chikate
Rajeev Chikate
CRChandrashekhar V. Rode
Chandrashekhar V. Rode
KPKishore M. Paknikar
Kishore M. Paknikar

20 March 2018 in Green Chemistry
Verified
Journal Article
Closed access
PDF file
NDNandan S. Date
Nandan S. Date
AHAmol M. Hengne
Amol M. Hengne
KHK.-W. Huang
K.-W. Huang
RCRajeev Chikate
Rajeev Chikate
CRChandrashekhar Vasant Rode
Chandrashekhar Vasant Rode
Various iridium supported carbon catalysts were prepared and screened for the direct hydrogenation of furfural (FFR) to 2-methyl furan (2-MF). Amongst these, 5% Ir/C showed excellent results with complete FFR conversion and highest selectivity of 95% to 2-MF at a very low H2 pressure of 100 psig. Metallic (Ir°) and oxide (IrO2) phases of Ir catalyzed the first step hydrogenation involving FFR to FAL and subsequent hydrogenation to 2-MF, respectively. This was confirmed by XPS analysis and some control experiments. At a low temperature of 140 °C, almost equal selectivities of FAL (42%) and 2-MF (43%) were observed, while the higher temperature (220 °C) favored selective hydrodeoxygenation. At optimized temperature, 2-MF was formed selectively while higher pressure and higher catalyst loading favored ring hydrogenation of furfural rather than side chain hydrogenation. With the combination of several control experimental results and detailed catalyst characterization, a plausible reaction pathway has been proposed for the selective formation of 2-MF. The selectivity to various other products in FFR hydrogenation can be manipulated by tailoring the reaction conditions over the same catalyst.

1 August 2011 in Chemical Engineering Journal
Verified
Journal Article
Closed access
SMSatish Meshram
Satish Meshram
RLRohan Limaye
Rohan Limaye
SGShailesh Ghodke
Shailesh Ghodke
SNShachi Nigam
Shachi Nigam
SSShirish Sonawane
Shirish Sonawane
RCRajeev Chikate
Rajeev Chikate

1 May 2011 in Applied Catalysis B: Environment and Energy
Verified
Journal Article
Closed access
BKBrijesh S. Kadu
Brijesh S. Kadu
YSYogesh D. Sathe
Yogesh D. Sathe
AIAbhijit B. Ingle
Abhijit B. Ingle
RCRajeev Chikate
Rajeev Chikate
KPKashinath R. Patil
Kashinath R. Patil
CRChandrashekhar V. Rode
Chandrashekhar V. Rode