Over the past 10 years (2005–2014), ground-level O₃ in Hong Kong has consistently increased in all seasons except winter, despite the yearly reduction of its precursors, i.e. nitrogen oxides (NO_x = NO + NO₂), total volatile organic compounds (TVOCs), and carbon monoxide (CO). To explain the contradictory phenomena, an observation-based box model (OBM) coupled with CB05 mechanism was applied in order to understand the influence of both locally produced O₃ and regional transport. The simulation of locally produced O₃ showed an increasing trend in spring, a decreasing trend in autumn, and no changes in summer and winter. The O₃ increase in spring was caused by the net effect of more rapid decrease in NO titration and unchanged TVOC reactivity despite decreased TVOC mixing ratios, while the decreased local O₃ formation in autumn was mainly due to the reduction of aromatic VOC mixing ratios and the TVOC reactivity and much slower decrease in NO titration. However, the decreased in situ O₃ formation in autumn was overridden by the regional contribution, resulting in elevated O₃ observations. Furthermore, the OBM-derived relative incremental reactivity indicated that the O₃ formation was VOC-limited in all seasons, and that the long-term O₃ formation was more sensitive to VOCs and less to NO_x and CO in the past 10 years. In addition, the OBM results found that the contributions of aromatics to O₃ formation decreased in all seasons of these years, particularly in autumn, probably due to the effective control of solvent-related sources. In contrast, the contributions of alkenes increased, suggesting a continuing need to reduce traffic emissions. The findings provide updated information on photochemical pollution and its impact in Hong Kong.

To investigate the atmospheric oxidative capacity (AOC) in forested high mountain areas adjacent to the photochemistry-active Pearl River Delta (PRD) region in southern China, one-month online observations of isoprene and its oxidation products methyl vinyl ketone (MVK) and methacrolein (MACR) were conducted at a national background station in Nanling Mountains in summer 2016. The results showed that the observed daytime isoprene levels (377±46 pptv) were significantly lower in comparison with other forest sites within and outside China, although the sampling site was surrounded with subtropical evergreen broad-leaved trees which are strong isoprene emitters. Also, high daytime (MVK + MACR) ∕ isoprene ratios (1.9±0.5) were observed. Based on the observations, we hypothesized that the lower isoprene levels in the study forest might be attributable to a strong AOC in relation to the elevated regional complex air pollution. In further data analyses, high site-level concentrations of daytime OH (7.3±0.5×10⁶ molecules cm⁻³) and nighttime NO₃ radicals (6.0±0.5×10⁸ molecules cm⁻³) were estimated by using a photochemical box model incorporating the master chemical mechanism (PBM-MCM), and high regional mixing ratios of OH (19.7±2.3×10⁶ molecules cm⁻³) during 09:00–15:00 LT were also obtained by applying a parameterization method with measured aromatic hydrocarbons. And besides, high initial mixing ratios (1213±108 pptv) and short atmospheric reaction time (0.27 h) of isoprene during the day were derived by a sequential reaction approach. All these indicate that isoprene was rapidly and highly oxidized in this forest, which supports our hypothesis. The study suggests that the complex air pollution in the PRD may have significantly elevated the background AOC of the adjacent forests, and probably affects the regional air quality and ecological environment in the long term. The feedback of forest ecosystems to the increasing AOC in southern China warrants further studies.

(1) Background: As the most common eye disease diagnosed in emergency departments, conjunctivitis has caused serious health and economic burdens worldwide. However, whether air pollution may be a risk factor for conjunctivitis is still inconsistent among current evidence. (2) Methods: We searched the literature on the relationship between air pollution and conjunctivitis in multiple English databases before 18 March 2019. Meta-analysis, meta-regression, and funnel plots were used to integrate the data, identify the sources of bias, and determine the publication bias, respectively. (3) Results: A total of 2450 papers were found, 12 of which were finally included. The pooled relative risk for each 10 μg/m³ increase of air pollution on conjunctivitis was 1.0006 (95%CI: 0.9993–1.0019) for CO, 1.0287 (1.0120–1.0457) for NO₂, 1.0089 (1.0030–1.0149) for O₃, 1.0004 (0.9976–1.0032) for PM_2.5, 1.0033 (0.9982–1.0083) for PM₁₀, and 1.0045 (0.9908–1.0185) for SO₂. In the subgroup, PM_2.5 and O₃ had a greater impact on conjunctivitis risk in women than in men, and people <18 years old than those ≥18 years old. Relative humidity significantly modified the risk of O₃ on conjunctivitis (p = 0.023), explaining 45% of the between-study heterogeneity. (4) Conclusion: Globally, air pollution has considerable health risks for conjunctivitis. Females and the youth were more vulnerable to PM_2.5, NO₂, and O₃. Reductions of air pollution levels are still warranted to protect the vulnerable populations.