A new synthetic approach towards the preparation of functionalised, soluble, donor–acceptor (DA) alkylbithiophene derivatives of oxadiazole, thiadiazole and triazole is reported. Taking advantage of the Fiesselmann reaction, reactive bithiophene synthons having alkyl or alkoxy substituents at designated positions are prepared. Following a synthetic strategy, featuring the bottom-up approach, sequential structural elements are built, starting from a simple thiophene compound, until the target molecule is obtained, all in good yield. Supplementing the well established methods of oxadiazole and thiadiazole synthesis, efficient ring closure reaction affording a 4H-1,2,4-triazole unit is presented. All target ambipolar compounds display strong photoluminescence with measured quantum yields up to 0.59. Modification of the demonstrated synthetic routes may be exploited for the preparation of longer, specifically functionalised oligothiophenes, coupled to other heteroaromatic cores.

Tungstate-containing aluminum oxide is suitable as a catalyst support for hydrodeoxygenation of sunflower oil, ensuring 81–83 wt % yield of liquid products at 380°С, 4.0 MPa, and feed space velocity...

MnO_x-CeO₂, MnO_x-ZrO₂, MnO_x-ZrO₂-CeO₂ oxides with the Mn/(Zr + Ce + Mn) molar ratio of 0.3 were synthesized by coprecipitation method followed by calcination in the temperature range of 400–800 °C and characterized by XRD, N₂ adsorption, TPR, TEM, and EPR. The catalytic activity was tested in the CO oxidation reaction. It was found that MnO_x-CeO₂, MnO_x-ZrO₂-CeO₂, MnO_x-ZrO₂ catalysts, calcined at 400–500 °C, 650–700 °C and 500–650 °C, respectively, show the highest catalytic activity in the reaction of CO oxidation. According to XRD and TEM results, thermal stability of catalysts is determined by the temperature of decomposition of the solid solution Mn_x(Ce,Zr)_1−xO₂. The TPR-H₂ and EPR methods showed that the high activity in CO oxidation correlates with the content of easily reduced fine MnO_x particles in the samples and the presence of paramagnetic defects in the form of oxygen vacancies. The maximum activity for each series of catalysts is associated with the start of solid solution decomposition. Formation of active phase shifts to the high-temperature region with the addition of zirconium to the MnO_x-CeO₂ catalyst.

The acidity of a series of borate-containing aluminum oxide samples with the concentrations of BO from 0.9 to 27.5 wt % and Pt-containing catalysts obtained on their basis was studied by spin probe EPR spectroscopy. With the use of anthracene and the TEMPO nitroxide radical as probe molecules, it was established that an increase in the BO content of the BO–AlO and Pt/BO–AlO systems leads to a symbatic increase in the number of medium-strength Brønsted acid sites (BASs). In this case, the yields of target hydroisomerization products (isoheptanes and methylcyclopentane) correlate with the number of BASs.