Photocatalysis plays a vital role in sustainable energy conversion and environmental remediation because of its economic, eco-friendly, and effective characteristics. Nitrogen-rich graphitic carbon nitride (g-C₃N₅) has received worldwide interest owing to its facile accessibility, metal-free nature, and appealing electronic band structure. This review summarizes the latest progress for g-C₃N₅-based photocatalysts in energy and environmental applications. It begins with the synthesis of pristine g-C₃N₅ materials with various topologies, followed by several engineering strategies for g-C₃N₅, such as elemental doping, defect engineering, and heterojunction creation. In addition, the applications in energy conversion (H₂ evolution, CO₂ reduction, and N₂ fixation) and environmental remediation (NO purification and aqueous pollutant degradation) are discussed. Finally, a summary and some inspiring perspectives on the challenges and possibilities of g-C₃N₅-based materials are presented. It is believed that this review will promote the development of emerging g-C₃N₅-based photocatalysts for more efficiency in energy conversion and environmental remediation.

Thiophene ring implanted two-dimensional carbon nitride nanosheets (2D Th_ing-CNNS) with dramatically double elevated n → π* electronic transitions were synthesized. 2D Th_ing-CNNS exhibited efficient photocatalytic bisphenol-A degradation.