The mining and leaching processes of rare-earth mines can include the entry of potentially toxic elements (PTEs) into the environment, causing ecological risks and endangering human health. However, the identification of ecological risks and sources of PTEs in rare-earth mining areas is less comprehensive. Hence, we determine the PTE (Co, Cr, Cu, Mn, Ni, Pb, Zn, V) content in soils around rare-earth mining areas in the south and analyze the ecological health risks, distribution characteristics, and sources of PTEs in the study area using various indices and models. The results showed that the average concentrations of Co, Mn, Ni, Pb and Zn were higher than the soil background values, with a maximum of 1.62 times. The spatial distribution of PTEs was not homogeneous and the hot spots were mostly located near roads and mining areas. The ecological risk index and the non-carcinogenic index showed that the contribution was mainly from Co, Pb, and Cr, which accounted for more than 90%. Correlation analysis and PMF models indicated that eight PTEs were positively correlated, and rare-earth mining operations (concentration of 22.85%) may have caused Pb and Cu enrichment in soils in the area, while other anthropogenic sources of pollution were industrial emissions and agricultural pollution. The results of the study can provide a scientific basis for environmental-pollution assessment and prevention in rare-earth mining cities.
Effects of landscape patterns or topographic features on the river water environment have been broadly studied to control non-point source (NPS) pollution and to cut off potential pathways for pollutants to affect human health. However, spatio-temporal dynamics and scale effects with respect to the impact of landscape patterns and topographic features on the aquatic environment over successive years have not been elucidated. In this study, water quality parameters and land cover data for three consecutive years mainly in Tangshan City, located in the northeast of the Haihe River Basin, China, were obtained to determine the associations between landscape patterns and topographic features with the water environment. Results indicated that seasonal differences in dissolved oxygen (DO) and total nitrogen (TN) were significant (p < 0.001), and spatial variation was generally observed for each water quality parameter. Redundancy analysis revealed that landscape patterns and topographic features have different impacts on the aquatic environment as seasonal spans and spatial scales change. Overall, the best explanatory variables explained an average of 58.6% of the variation in water quality at various spatial scales over the two seasons. Topographic features made a greater contribution to river water quality changes at the buffer scale; conversely, at the catchment scale, water quality changes stemmed primarily from differences in landscape composition and configuration. The landscape shape index of cropland (LSIcrop) was an important factor influencing seasonal river water quality changes at various spatial scales. These results suggest that considering landscape connectivity at distinct spatial scales could enhance the understanding of the alteration of hydrological processes across multiple topographic features, which in turn has an impact on seasonal river water.
The fragile ecological environment of the Qinghai–Tibet Plateau (QTP) is significantly affected by human activities. This study employed a self-organizing map (SOM) for cluster analysis and positive matrix factorization (PMF) to trace the source of potentially toxic elements (PTEs) in the surface water of rivers. The results revealed that the average concentration of PTEs in the rivers was generally low. However, at some sampling points, especially in areas near the Qarhan Salt Lake, the content of Cu, Hg, and Ni were high. The water quality index (WQI), contamination factor (CF), and modified contamination index (mCd) identified good water quality, while potential Ni in the Quanji and Golmud River basins were the primary contaminants of concern. The potential ecological risk index (PERI) showed a low ecological risk. The SOM yielded four clusters of water PTEs, including Hg, Cu-Ni, Pb-Cd-Zn, and As. PMF model further revealed PTE sources, with industrial sources (39.73%) as the primary anthropogenic factor, followed by natural weathering (33.44%), vehicle emissions (21.52%), and atmospheric deposition (5.31%). This study laid the foundation for the ecological monitoring of rivers on the QTP and provided a reference for balancing industrial development and ecological protection in Qarhan Salt Lake areas.