In order to explore the emission characteristics of volatile organic compounds (VOCs) and different VOC components in airtight environments, polyvinyl chloride laminated plywood (PVC-P), melamine-impregnated paper laminated plywood (MI-P), water-based paint laminated plywood (WP-P) and unfinished plywood (UF-P) were tested as materials in 15 L small environment cabins. VOCs were collected after being sealed for 2 h, 4 h, 6 h, 8 h, 12 h, 18 h, 24 h and 30 h under different loading ratios (1 m²/m³, 1.5 m²/m³, 2 m²/m³, 2.5 m²/m³) and analyzed using a gas chromatography–mass spectrometer. The results show that VOCs gradually increased and tended to be saturated with the increase of time in an airtight environment. The saturation of veneered plywood was faster than unfinished plywood and the pollution degree of three kinds of veneered plywood from lowest to highest was in order of PVC-P, MI-P, WP-P. Aromatic hydrocarbons account for more than half of VOC concentration, and was most obviously affected by the loading ratios. Surfaced laminated plywood can reduce the emission of aromatic hydrocarbons, but also increases the amount of other compounds released. The concentration of VOC-components shows different characteristic curves at different loading ratios due to the influence of decorative materials.

Because the surface of MDF is not aesthetically pleasing, it usually needs to be veneered and then painted, but such a board releases harmful VOCs, among which Benzene Series is the most harmful. Benzene and its series are a group of carcinogenic compounds. With the diluents of nitrocellulose (NC)-lacquered MDF as the research objects, the release of the Benzene Series was studied to provide a scientific basis for pollution control and a reference for eco-friendly paint production. The attenuant of NC paint, anhydrous ethanol, ethyl acetate and solvents mixed with different alcohol ester ratios were used as diluents in NC lacquer. Two kinds of wood-veneered MDF with different thickness (18 mm and 8 mm) were coated with NC lacquer and analyzed in the experiment. The gas was collected using a small environmental chamber and the Benzene Series was analyzed using GC-MS. The concentration of Benzene Series released by MDF was 316.24 μg·m⁻³, and that of the NC-lacquered MDF with thicknesses of 18 mm and 8 mm were 284.44 μg·m⁻³ and 281.06 μg·m⁻³, respectively. The MDF released 14 kinds of Benzene Series, and the NC-lacquered MDF with two thicknesses released 18 kinds of it. The release concentration order of Benzene Series in NC-lacquered MDF with different diluents of the 18 mm thick panel was NC-M, NC-A, and NC-E from high to low. The lowest concentration of it occurred when the ratio of anhydrous ethanol to ethyl acetate was 1:3, and the lowest amount of components were at the ratio of 1:2. The concentration of Benzene Series released by MDF is higher than that released by the NC-lacquered MDF. Thickness has no effect on the type of release. The thicker MDF was, the higher the concentration was. The alcohol and ester thinner can control the release of Benzene Series from the source, and the optimal mixing ratio was 1:3.