Lithium-ion batteries have become the primary electrical energy storage device in commercial and industrial applications due to their high energy/power density, high reliability, and long service life. It is essential to estimate the state of health (SOH) of batteries to ensure safety, optimize better energy efficiency and enhance the battery life-cycle management. This paper presents a comprehensive review of SOH estimation methods, including experimental approaches, model-based methods, and machine learning algorithms. A critical and in-depth analysis of the advantages and limitations of each method is presented. The various techniques are systematically classified and compared for the purpose of facilitating understanding and further research. Furthermore, the paper emphasizes the prospect of using a knowledge graph-based framework for battery data management, multi-model fusion, and cooperative edge-cloud platform for intelligent battery management systems (BMS).
The accurate estimation of the battery state of health (SOH) is crucial for the dependability and safety of battery management systems (BMS). The generality of existing SOH estimation methods is limited as they tend to primarily consider information from single-source features. Therefore, a novel method for integrating multi-feature collaborative analysis with deep learning-based approaches is proposed in this research. First, several battery degradation features are obtained through differential thermal voltammetry (DTV) analysis, singular value decomposition (SVD), incremental capacity analysis (ICA), and terminal voltage characteristic (TVC) analysis. The features highly related to SOH are selected as inputs for the deep learning model based on the results of a Pearson correlation analysis. The SOH estimation is achieved by developing a deep learning framework cored by long short-term memory (LSTM) neural network (NN), which integrates multi-source features as an input. A suggested method is validated using NASA and Oxford Battery Degradation datasets. The results demonstrate that the presented model provides great SOH estimation accuracy and generality, where the maximum root mean square error (RMSE) is less than 1%. Based on a cloud computing platform, the proposed method can be applied to provide a real-time prediction of battery health, with the potential to enhance battery full lifespan management.
Safety issues are one of the main limitations for further application of lithium-ion batteries, and battery degradation is an important causative factor. However, current state-of-health (SOH) estimation methods are mostly developed for a single feature and a single operating condition as well as a single battery material system, which consequently makes it difficult to guarantee robustness and generalization. This paper proposes a data-driven and multi-feature collaborative SOH estimation method based on equal voltage interval discharge time, incremental capacity (IC) and differential thermal voltammetry (DTV) analysis for feature extraction. The deep learning model is constructed based on bi-directional long short-term memory (Bi-LSTM) with the addition of attention mechanism (AM) to focus on the important parts of the features. The proposed method is validated based on a NASA dataset and Oxford University dataset, and the results show that the proposed method has high accuracy and strong robustness. The estimated root mean squared error (RMSE) are below 0.7% and 0.3%, respectively. Compared to single features, the collaboration between multiple features and AM resulted in a 25% error improvement, and the capacity rebound is well captured. The proposed method has the potential to be applied online in an end-cloud collaboration system.
The accurate estimation of the state of charge (SOC) plays a crucial role in ensuring the range of electric vehicles (EVs) and the reliability of the EVs battery. However, due to the dynamic working conditions in the implementation of EVs and the limitation of the onboard BMS computational force, it is challenging to achieve a reliable, high-accuracy and real-time online battery SOC estimation under diverse working scenarios. Therefore, this study proposes an end-cloud collaboration approach of lithium-ion batteries online estimate SOC. On the cloud-side, a deep learning model constructed based on CNN-LSTM is deployed, and on the end-side, the coulomb counting method and Kalman’s filter are deployed. The estimation results at both sides are fused through the Kalman filtering algorithm, realizing high-accuracy and real-time online estimation of SOC. The proposed approach is evaluated with three dynamic driving profiles and the results demonstrate the proposed approach has high accuracy under different temperatures and initial errors, where the root means square error (RMSE) is lower than 1.5% and the maximum error is lower than 5%. Furthermore, this method could achieve high-accuracy and real-time SOC online estimation under the cyber hierarchy and interactional network (CHAIN) framework and can be extended to multi-state collaborative online estimation.
Accurate estimation of the State of Health (SOH) of lithium-ion batteries is crucial for ensuring their safe and reliable operation. Data-driven methods have shown excellent performance in estimating SOH, but obtaining high-quality and strongly correlated features remains a major challenge for these methods. Moreover, different features have varying importance in both spatial and temporal scales, and single data-driven models are unable to capture this information, leading to issues with attention dispersion. In this paper, we propose a data-driven method for SOH estimation leveraging the Bi-directional Long Short-Term Memory (Bi-LSTM) that uses the Differential Thermal Voltammetry (DTV) analysis to extract features, and incorporates attention mechanisms (AM) at both temporal and spatial scales to enable the model focusing on important information in the features. The proposed method is validated using the Oxford Battery degradation Dataset, and the results show that it achieves high accuracy and robustness in SOH estimation. The Root Mean Squared Error (RMSE) and Mean Absolute Error (MAE) are around 0.4% and 0.3%, respectively, indicating the potential for online application of the proposed method in the cyber hierarchy and interactional network (CHAIN) framework.
With rapid development of clean energy vehicles, the health diagnosis and prognosis of lithium batteries remain challenging for practical applications. Accurate state-of-health (SOH) and remaining useful life (RUL) estimation provides crucial information for improving the safety, reliability and longevity of batteries. In this paper, a fusion of deep-learning model and feature signal analysis methods are proposed to realize accurate and fast estimation of the health conditions for battery cathodes. Specifically, the long short-term memory (LSTM) network and differential thermal voltammetry (DTV) are utilized to verify our fusion method. Firstly, the DTV feature signal analysis is executed based on battery charging and discharging data, based on which useful feature variables are extracted with Pearson correlation analysis. Next, the deep-learning model is constructed and trained with the LSTM as the core based on timeseries datasets constructed with features. Finally, the validation and error analysis of proposed model are provided, showing a max mean absolute error of 0.6%. The proposed method enables highly accurate models for SOH and RUL estimation that can be potentially deployed on cloud-end for offline battery degradation tracking.