Ozone (O3), a strong oxidizing agent, has found widespread applications since its structure was confirmed by Schubbe in 1839. It can be produced through ultraviolet radiation, electrochemical methods, or dielectric barrier discharge (DBD), with DBD being the most efficient for large-scale production due to its high stability. Ozone is widely used in environmental management, particularly in water treatment, air pollution control, and soil remediation. In water treatment, ozone effectively removes microorganisms and contaminants without generating secondary pollutants. In air pollution control, it degrades organic compounds in industrial waste and neutralizes toxic gases in automobile exhausts. Ozone also breaks down persistent pollutants like polycyclic aromatic hydrocarbons in soil, improving soil quality. However, challenges remain related to ozone’s stability and high production costs. Beyond environmental uses, ozone is critical in industries and medicine. It helps remove pathogens and heavy metals in wastewater treatment, extends shelf life and deactivates mycotoxins in food processing, and shows promise in medical fields like orthopedics and cancer therapy. In the power industry, ozone plays a key role in water treatment and air purification. Overall, ozone technology offers significant potential for both environmental and industrial applications.
The sulfur-iodine (SI) cycle holds great promise as an alternative large-scale process for converting water into hydrogen without CO2 emissions. A major issue regarding the long-term stability and activity of the catalysts is their poor sulfur deactivation resistance in the HI feeding process. In this work, the effect of Ru addition for enhancing the activity and sulfur resistance of SiO2-supported Ni catalysts in the HI decomposition reaction has been investigated. The presence of H2SO4 molecules in the HI results in severe sulfur deactivation of the Ru-free Ni/SiO2 catalysts by blocking the active sites. However, Ni–Ru/SiO2 catalysts show higher catalytic activity without sulfur-poisoning by 25% and exhibit more superior catalytic performance than the Ru-free catalyst. The addition of Ru to the Ni/SiO2 catalyst promotes the stability and activity of the catalysts. The experimental trends in activity and sulfur tolerance are consistent with the theoretical modeling, with the catalytic activities existing in the order Ni/SiO2 < Ni–Ru/SiO2. The effect of Ru on the improvement in sulfur resistance over Ni-based catalysts is attributed to electronic factors, as evidenced by theory modeling analysis and detailed characterizations.
27 February 2018 in Journal of Energy Resources Technology
In order to implement the new strategy of national energy security, carbon peak will be realized during the 15th Five-Year Plan period and strive to basically achieve the strategic goal of carbon neutrality by 2050. A clean, low-carbon, safe and efficient energy system is needed to be built. This paper investigates the primary energy supply and consumption, analyses power generation structure and carbon emissions. Moreover, comparisons with typical carbon peak regions are conducted and foreign advanced experience is learned. To achieve the carbon neutrality, we need to limit the fossil energy use, improve the energy efficiency, develop the renewable energy and increase the terminal electrification rate.