Phosphogypsum is an industrial by-product from the wet preparation of phosphoric acid. Phosphorus building gypsum (PBG) can be obtained from phosphogypsum after high-thermal dehydration. Improving the mechanical properties of PBG is of great significance to extending its application range. In this paper, PBG was modified by adding nano-CaCO₃. Specifically, this study, conducted on 0.25–2% nano-CaCO₃-doped PBG, tested effects on the fluidity, setting time, absolute dry flexural strength, absolute dry compressive strength, water absorption and softening coefficient of PBG, followed by its microscopic analysis with SEM and XRD. The experimental results showed that, with an increase in nano-CaCO₃ content, the fluidity and setting time of PBG-based mixes were decreased. When the content was 2%, the fluidity was 120 mm, which was 33% lower than that of the blank group; the initial setting time was 485 s, which was 38% lower than that in the blank group; the final setting time was 1321 s, which was reduced by 29%. Nano-CaCO₃ evidently improved the absolute dry flexural strength, absolute dry compressive strength, water absorption and softening coefficient of PBG to a certain extent. When the content was 1%, the strengthening effect reached the optimum, with the absolute dry flexural strength and absolute dry compressive strength being increased to 8.1 MPa and 20.5 MPa, respectively, which were 50% and 24% higher than those of the blank group; when the content was 1.5%, the water absorption was 0.22, which was 33% lower than that of the blank group; when the content approached 0.75%, the softening coefficient reached the peak of 0.63, which was 66% higher than that of the blank group. Doping with nano-CaCO₃ could significantly improve the performance of PBG, which provides a new scheme for its modification.

Phosphogypsum is an industrial byproduct from the wet preparation of phosphoric acid. Phosphorus building gypsum can be obtained from phosphogypsum after high-thermal dehydration. This study aimed to analyze the influence of ball milling with different parameters on the strength of phosphorus building gypsum. In this paper, the absolute dry flexural strength and the absolute dry compressive strength of phosphorus building gypsum were compared under different mass ratios of material to ball, ball-milling speed, and ball-milling time, and the NSGM (1,4) model was applied to model and predict the strength of phosphorus building gypsum modified by ball milling. According to the research results, under the same mass ratio of material to ball and ball-milling speed, the absolute dry flexural strength and absolute dry compressive strength of phosphorus building gypsum firstly increased and then decreased with the increase in milling time. The NSGM (1,4) model established in this paper could effectively simulate and predict the absolute dry flexural strength and the absolute dry compressive strength of the ball-milling-modified phosphorus building gypsum; the average relative simulation errors were 12.38% and 13.77%, and the average relative prediction errors were 6.30% and 12.47%.