Alkaline igneous complexes host deposits of rare earth elements (REE), which represent one of the most economically important resources of heavy REE and Yttrium (Y). The hosts are differentiated rocks ranging from nepheline syenites and trachytes to peralkaline granites. These complexes usually occur in continental within-plate tectonic settings associated with rifts, faults, or hotspot magmatism. The REE mineralization is found in layered alkaline complexes, granitic stocks, and late-stages dikes and rarely trachytic volcanic and volcaniclastic deposits. The bulk of REE is present in accessory minerals, which can reach percentage levels in mineralized zones. The mineralization contains various REE-bearing minerals that can display complex replacement textures. Main REE minerals present in these deposits are bastnäsite, eudialyte, loparite, gittinsite, xenotime, monazite, zircon, and fergusonite. The parent magmas of alkaline igneous complexes are derived from partial melts of mantle sources. Protracted fractional crystallization of the magma led to an enrichment in REE, particularly in the late stages of magma evolution. The primary magmatic mineralization is commonly overprinted (remobilized and enriched) by late magmatic to hydrothermal fluids. Elevated abundances of U and Th in the deposits make a gamma-ray (radiometric) survey an important exploration tool, but also represent a significant environmental challenge for exploitation.

Dykes of calc-alkaline lamprophyre cutting granite of the Hercynian Jebilet Massif of the Moroccan Meseta (western Morocco) contain crustal xenoliths. The xenoliths range in composition from mafic (cognate cumulates) and upper crustal granitic rocks through gneisses to middle crustal felsic granulites. SHRIMP U–Th–Pb zircon analyses of these rocks indicate that the dykes were likely intruded during Middle Triassic times (∼235 Ma), whereas the xenoliths contain zircons with concordant Carboniferous–Early Permian, Neoproterozoic and Palaeoproterozoic ages (280–328 Ma, c. 540–615 Ma, 700 Ma and ∼2000 Ma). The 280–328 Ma ages appear to record synchronous intrusive and high-grade (up to granulite facies) Variscan metamorphic events, suggesting that high-grade metamorphism may have facilitated the S-type granitic magmatism. On the other hand, the ∼540–615 Ma, 700 Ma and 2000 Ma ages correspond with Pan-African and Eburnian orogenic events recorded in the West African Craton. In a Triassic reconstruction, Morocco is juxtaposed against Nova Scotia (Canada), and some have proposed that the basement of the easternmost terrane (Meguma terrane) is a piece of the West African craton. However, lower crustal xenoliths from Devonian dykes (∼370 Ma) cutting the Meguma terrane have yielded Late Devonian, Neo- and Mesoproterozoic ages (378 Ma, 575–629 Ma, ∼880–1050 Ma and ∼1530 Ma). The presence of ∼1 Ga ages suggests that the basement of the Meguma terrane is Avalonian rather than West African, implying that in a Pangean reconstruction, the Rheic Ocean suture between NW Africa and Maritime Canada coincides with the Atlantic Ocean.

Highly evolved alkaline/peralkaline igneous rocks host deposits of rare earth elements (REE), including Y as well as Zr, Hf, Nb, Ta, U, and Th. The host rocks spanning from silica-undersaturated (nepheline syenites) to silica-oversaturated (granites) occur in intraplate tectonic environments, mainly in continental settings and are typically associated with rifting, faulting, and/or crustal extension. They range in age from Neoarchean/Paleoproterozoic to Mesozoic, but several significant deposits are of Mesoproterozoic age. The deposits/prospects can be subdivided into three types. The first is hosted by nepheline syenitic rocks of large, layered alkaline intrusions where the mineralization commonly occurs in layers rich in REE-bearing minerals, which mostly show cumulate textures (e.g., Thor Lake/Nechalacho, Canada; Ilimaussaq, Greenland; Lovozero, Russia; Kipawa, Canada; Norra Kärr, Sweden; Pilanesberg, South Africa). The second type includes mineralization in peralkaline granitic rocks where REE-bearing minerals are usually disseminated. The mineralization is typically hosted by pegmatites (including the Nb-Y-F type), felsic dikes, and minor granitic intrusions (e.g., Strange Lake, Canada; Khaldzan-Buregtey, Mongolia; Ghurayyah, Saudi Arabia; Bokan, Alaska, United States). The third type is disseminated, very fine grained, and hosted by peralkaline felsic volcanic/volcaniclastic rocks, mostly of trachytic composition (e.g., Dubbo Zirconia and Brockman/Hastings, Australia). The bulk of the REE is present in ore/accessory minerals which in some mineralized zones, particularly in cumulate rocks from alkaline complexes, can reach >10 vol %. Mineralization is composed of a variety of REE-bearing minerals, which frequently show complex replacement textures. They include fluorocarbonates, phosphates, silicates, and oxides. Economically most important are bastnäsite, monazite, xenotime, loparite, eudialyte, synchysite, and parasite. Many other minerals are either sparse or it is difficult with present technology to profitably extract REE from them on a commercial scale. Compared to carbonatite-hosted REE deposits, the REE mineralization in alkaline/peralkaline complexes has lower light REE concentrations but has commonly higher contents of heavy REE and Y and shows a relative depletion of Eu. Elevated concentrations of U and Th in the ore assemblages make gamma-ray (radiometric) surveys an important exploration tool. The host peralkaline (granitic, trachytic, and nepheline syenitic) magmas undergo extensive fractional crystallization, which is protracted in part due to high contents of halogens and alkalis. The REE mineralization in these rocks is related to late stages of magma evolution and typically records two mineralization periods. The first mineralization period produces the primary magmatic ore assemblages, which are associated with the crystallization of fractionated peralkaline magma rich in rare metals. This assemblage is commonly overprinted during the second mineralization period by the late magmatic to hydrothermal fluids, which remobilize and enrich the original ore. The parent magmas are derived from a metasomatically enriched mantle-related lithospheric source by very low degrees of partial melting triggered probably by uplift (adiabatic) or mantle plume activity. The rare metal deposits/mineralization related to peralkaline igneous rocks represent one of the most economically important resources of heavy REE including Y. In addition to REE, some of these deposits contain economically valuable concentrations of other rare metals including Zr, Nb, Ta, Hf, Be, U, and Th, as well as phosphates.

The Jurassic Bokan Mountain complex (BMC), composed of arfvedsonite and/or aegirine-bearing peralkaline A-type granitic rocks, is a circular body about 3 km in diameter located in southeastern Alaska. Like many other highly fractionated granitic bodies, the BMC granites were affected by late magmatic or post-magmatic processes, which, however, did not modify the contents of major elements. The granitic rocks are distinctly enriched in high-field-strength elements (HFSEs), rare earth elements (REEs), Y, Th, and U but depleted in Ba, Sr, and Eu and have high positive ɛ_Nd(T) values. Unlike the variations in the major elements, Sr and Ba, which can be accounted by fractional crystallization, the abundance of REE, Y, HFSE, U, and Th (the elements which are hosted in accessory phases) were modified by F-rich hydrothermal fluids. The BMC hosts significant rare metal mineralization related to the late-stage crystallization history of the complex involving late magmatic and/or post-magmatic fluids. The mineralization includes two types: (1) a U–Th deposit which was exploited at the former Ross-Adams mine and (2) REE and Y mineralization mostly hosted in felsic dikes. Thermodynamic modelling of granites and spatially associated mafic rocks using the programme Rhyolite-MELTS implies that the granites can be derived from the mafic rocks by fractional crystallization. It is suggested that such a process (i.e. derivation of peralkaline granitic magma from the alkali or transitional basaltic magmas derived by partial melting from a lithospheric source metasomatically enriched in rare metals) can be invoked for other peralkaline granitic rocks hosting rare metal deposits.