In this study, the effect of limestone content on the mechanical performance and the heat of hydration of ordinary Portland cement (OPC) was investigated. Changes in the phase assemblage were analyzed through XRD and thermodynamic modeling. The purpose of the study was to identify the optimal limestone content in OPC. As a result of the experiment, all samples were found to have equal fluidity. Increasing the limestone content accelerated the hydration of the cement before approximately 13 h and shortened the setting time due to the acceleration of the initial hydration reaction. The compressive strength of the cement mortar showed a dilution effect, with lower compressive strength compared to the reference sample at an early age, but it gradually recovered at a later age. This is because, as shown in the XRD and thermodynamic modeling results, the carboaluminate phases formed due to the chemical effect of limestone contributed to the development of compressive strength. As a result, within the scope of this study, it is believed that maintaining the limestone content in OPC within 10% is optimal to minimize quality degradation.

Compared to the bottom ash obtained by a water-cooling system (wBA), dry process bottom ash (dBA) makes hardly any unburnt carbon because of its stay time at the bottom of the boiler and contains less chloride because there is no contact with seawater. Accordingly, to identify the chemical stability of dBA as a lightweight aggregate for construction purposes, the chemical properties of dBA were evaluated through the following process of the reviewing engineering properties of a lightweight aggregate (LWA). Typically, river gravel and crushed gravel have been used as coarse aggregates due to their physical and chemical stability. The coal ash and LWA, however, have a variety of chemical compositions, and they have specific chemical properties including SO₃, unburnt coal and heavy metal content. As the minimum requirement to use the coal ash and lightweight aggregate with various chemical properties for concrete aggregate, the loss on ignition, the SO₃ content and the amount of chloride should be examined, and it is also necessary to examine heavy metal leaching even though it is not included in the standard specifications in Korea. Based on the results, it is believed that there are no significant physical and chemical problems using dBA as a lightweight aggregate for concrete.

We have examined whether the copper reduction slag (CRS) generated after recovering valuable metals from copper slag (CS) by reduction process can be used as supplementary cementitious materials (SCMs). According to the test results, the Cu secondary slag with low Fe, Cu, and heavy metal contents had a suitable oxide composition for using as a SCM. CRS showed better grinding efficiency than that of ground blast furnace slag (GGBS). Ground CRS contributed to the formation of tobermorite under autoclaved curing conditions. The compressive strength of CRS mortar replacing 50 % of OPC generated 93 % of that of the OPC mortar. Based on the results of this study, we found that the CRS has highly appropriate engineering characteristics for using as SCMs for concrete. In addition, it is judged that the method of using secondary slag as a material for precast concrete produced under hydrothermal conditions can greatly contribute to the construction process of buildings by securing mechanical performance.

The cement industry is responsible for a significant portion of global CO₂ emissions, primarily due to the decarbonatization of limestone during clinker production. To mitigate this environmental impact, this study investigated the feasibility of using waste concrete fine powder, produced during the recycling of waste concrete, as a decarbonized raw material in cement clinker production. As a decarbonized material, waste concrete fine powder presents a valuable opportunity to reduce CO₂ emissions typically produced during the decarbonatization of limestone in clinker production. In addition, its use supports the recycling of construction waste, contributing to both emissions reduction and resource sustainability. In this study, samples were collected from 20 intermediate treatment plants in South Korea, where the chemical composition, particle size distribution, and carbonation rate of the fine powders were analyzed. The experimental results show that the properties of waste concrete fine powder vary significantly depending on the recycling process. Road construction aggregate production plants, which typically involve two to three crushing stages, produce fine powders with higher CaO content (28–31%) and consistent particle size distributions. In contrast, plants producing aggregates for concrete, which involve four to six crushing stages, produce powders with lower CaO content (around 20%) and greater variability in particle size. The average carbonation rate of 7.44% suggests that these fine powders can replace limestone in clinker production. It is estimated that substituting 5% of limestone with waste concrete fine powder could reduce CO₂ emissions from limestone decarbonatization by approximately 952,560 tons in 2023, representing a 3.34% decrease in total emissions from clinker production. However, it is important to note that the CO₂ emissions reduction calculation is not from a lifecycle perspective, without considering the energy-related emissions from recycling waste concrete fine powder. Nevertheless, this study highlights the potential for waste concrete fine powder to serve as a sustainable raw material for the cement industry, contributing to both CO₂ reduction and efficient recycling of construction waste.

In this experimental study, tests were conducted to obtain the CaO/SiO₂ (C/S) molar ratio that minimizes the micropores of hardened concrete. To this end, the compressive strength, thermogravimetric analysis (TGA), and microporous structure of hardened concrete were investigated using concrete specimens made with silica fume and quartz powder under high-temperature/high-pressure conditions. The tests yielded the following results: (1) the highest compressive strength (200 MP) was exhibited in the C/S molar ratio range of 0.7–0.9, and lower compressive strength was exhibited in the C/S molar ratio ranges of ≤ 0.6 and ≥ 0.95; (2) the productivity of calcium silicate hydrate (C-S-H) tended to increase in proportion to the C/S molar ratio in all specimens; (3) the microstructure was measured using mercury intrusion porosimetry (MIP), and the maximum total porosity of specimens was calculated to be 10%. As the C/S molar ratio increased, the total porosity decreased, as did the pore diameter and threshold pore diameter. Thus, C/S molar ratio was found to be a major factor affecting the compressive strength and microporous structure of autoclave-cured cement and the optimal mechanical properties were exhibited in the C/S molar ratio of 0.8–0.9. However, the reactivity varies depending on the material used and curing conditions employed. Therefore, the hydration products obtained using the curing conditions need to be investigated further.