The Mediterranean coastal aquifer system of the Grombalia basin (NE Tunisia) offers immense potential as a source of fresh water for agriculture, industry, and drinking water supply. Nonetheless, due to its intricate hydrogeological characteristics and the prevailing issue of groundwater salinity, comprehending its groundwater system behavior becomes crucial for the effective and sustainable management of this aquifer system. Based on the hydrogeological characterization of the Grombalia basin, a novel 3D hydrogeological conceptual model was developed to enhance the understanding of its complex aquifer system. The integration of insights from geological, hydrogeological, hydrodynamic, and hydrochemical components facilitated the construction of the hydrogeological conceptual model. Although the model’s validity faced initial uncertainties due to spatial interpolation of lithological sequences, this study’s thorough and encompassing hydrogeological investigation overcame these limitations. As a result, a more informed comprehension of the aquifer system complexities was achieved. This study reveals that the basin is underlain by an extensive, cohesive Mio–Plio–Quaternary aquifer system. The model demonstrates vertical and lateral hydrogeological continuity between the Quaternary and underlying Mio–Pliocene deposits, enabling groundwater flow and exchange between these layers. Over-abstraction of the Mio–Plio–Quaternary aquifer system has led to a significant drop in piezometric levels and raised the risk of seawater intrusion. These findings emphasize the critical necessity of taking into account the interconnections among hydrogeological units to ensure sustainable groundwater management. The developed conceptual model offers a key tool for understanding the hydrodynamic functioning of the Grombalia aquifer system with a view toward guiding future groundwater management strategies. The application of this approach in the Grombalia basin suggests its potential applicability to other regional aquifers facing comparable challenges.

Phosphate rock is a vital natural resource classified by the European Commission as a critical raw material (CRM), extensively mined for its agricultural, industrial, and technological applications. While primarily used in fertilizer production, phosphate deposits also contain significant concentrations of trace metals, notably rare earth elements (REE), which are essential for renewable energy, electronics, and defense technologies. In response to growing demand, the recovery of REE from phosphate ores and processing by-products, particularly phosphogypsum (PG), has gained international attention. This review provides a comprehensive analysis of the global phosphate industry, examining production trends, market dynamics, and the environmental implications of phosphate processing. Special focus is placed on the geochemical behavior and mineralogical associations of REE within phosphate ores and industrial residues, namely PG and purification sludge. Although often treated as waste, these by-products represent underexplored secondary resources for REE recovery. Technological advancements in hydrometallurgical, solvometallurgical, and bioleaching methods have demonstrated promising recovery efficiencies, with some pilot-scale studies exceeding 70%–80%. However, large-scale implementation remains limited due to economic, technical, and regulatory constraints. The circular economy framework offers a pathway to enhance resource efficiency and reduce environmental impact. By integrating innovative extraction technologies, strengthening regulatory oversight, and adopting sustainable waste management practices, phosphate-rich countries can transform environmental liabilities into strategic assets. This review concludes by identifying key knowledge gaps and suggesting future research directions to optimize REE recovery from phosphate deposits and associated by-products, contributing to global supply security, economic diversification, and environmental sustainability.

This study examines the effects of natural organic matter (NOM) and dissolved solids on fluoride (F⁻) retention in polyelectrolyte multilayer-based hollow-fiber nanofiltration membranes (dNF40). Lab-scale filtration experiments were conducted under varying operating conditions (initial salt concentration, NOM concentration, permeate flux, crossflow velocity, and recovery rate). dNF40 membranes exhibited F⁻ retention above 70% ± 1.2 in the absence of NOM and competing ions. However, when filtering synthetic model water (SMW) designed to simulate groundwater contaminated with high total dissolved solids (TDSs) and NOM, F⁻ retention decreased to approximately 60% ± 0.7, which was generally attributed to ion competition. Furthermore, despite limited declines in normalized permeability, the addition of NOM to SMW notably deceased F⁻ retention in the steady state to~20% due to fouling effects. The facilitated transport of the divalent cations Ca²⁺ and Mg²⁺ could be observed, as they accumulated in the organic fouling layer. While SO₄²⁻ retention remained relatively stable, the retention of monovalent anions (NO₃⁻, Cl⁻, and F⁻) decreased substantially due to drag effects. Na⁺ retention improved slightly to maintain electroneutrality. Feed salinity was shown to significantly affect separation efficiency, with PEC layers undergoing swelling and certain structural changes as the ionic strength increased. During batch filtration experiments at varying recovery rates, the retention of monovalent anions further decreased, with F⁻ retention reducing to just ~10% at a 90% recovery rate. This study provides valuable insights into better understanding and optimizing the performance of PEC-based NF membranes across diverse water treatment scenarios.