Plastics production is increased recently due to their various applications such as construction, electronic, packaging and others. The rising in plastics demand lead to developed of recycling and energy recovery method to control plastic wastes. Recycling process is needs to be arranged according to resins, colors and transparency of all plastics. Energy dispersive X-ray fluorescence (EDXRF) was developed for the determination of the chemical composition in different plastics materials (with resin identification code) of PETE (1) or PET (01), HDPE (2) or PE-HD (02), V (3) or PVC (03), LDPE (4) or PE-LD, PP (5) or PP (06), PS (6) or PS (06) and Others (7) or O (07). XRF was measured elements such as Si, S, Cl, Fr, Ca, Ti, V, Fe, Cu, Zn, As, Kr, Zr, Nb, Mo and Nb in both k α and k β lines, where PP with high percentage in both PET and PVC plastics, which is highly hazardous. In addition, chemical compositions in percentages were detected for various plastics materials.