A newly developed cathode material, , was synthesized and characterized. X-ray diffraction results identified it as a cubic perovskite structure. Thermogravimetric results showed that lattice oxygen loss was about 2% in weight between 50 and 1000°C. Thermal expansion coefficient results in air and argon were extraordinarily high, with slope changes occurring at about 382 and 360°C, respectively. Electrical conductivity values were sufficient for cathode application with the maximum of about at 500°C in air and at 900°C in , correspondingly. Both thermal and electrical properties were closely associated with lattice oxygen behaviors and oxygen partial pressure.

Some perovskite ferrites suffer from phase decomposition in a reducing environment, and incorporation of high-valence cations, such as Nb⁵⁺ and Ti^4+/3+, is an effective method to stabilize the ferrites. Herein, we rationally introduce pentavalent tantalum on the B-site of La_0.8Sr_0.2FeO_3−δ (LSF) to prepare novel perovskites La_0.8Sr_0.2Fe_0.95Ta_0.05O_3−δ (LSFTa05) and La_0.8Sr_0.2Fe_0.9Ta_0.1O_3−δ (LSFTa10), and evaluate their electrochemical performance as SOFC anodes. The structural stability of LSF is notably improved but the oxygen vacancy content is decreased after Ta doping. LSFTa05 is the most promising anode among the three candidates due to its best performance after 50 h of operation (441.7 mW cm⁻² at 800 °C in wet H₂) and considerable coking and sulfur resistance. Finally, DFT calculations are performed to study the mechanisms of stability and conductivity of the ferrites with different Ta contents. Our work highlights that LSFTa05 is a high-performance and robust alternative perovskite anode, and could provide valuable insights into developing high-valence cation-stabilized perovskite anodes for SOFCs.