With the substantial increase in karst groundwater pollution, the pollution caused by heavy metal migration has become one of the hottest topics. The migration characteristics of heavy metals in karst groundwater are closely related to the geological environment in which they are found. Therefore, this review focuses on the migration characteristics of heavy metals in karst groundwater in southern and northern China and highlights the effect of different environmental contexts such as atmosphere (precipitation), vegetation, soil, rock, and aquifers on the behavior of heavy metals. It also summarizes existing research methods on heavy metal migration in karst groundwater. Meanwhile, current advances and the future perspectives on karst groundwater heavy metal migration will be presented. It is hoped that this review may shed light on the study of heavy metal migration in karst areas.

In this study, 24 surface water samples were collected from the main trunk/tributary of the Lijiang River during the wet season (April) and the dry season (December) in 2021. The total concentration of 11 heavy metal(loid)s (Al, Cu, Pb, Zn, Cr, Ni, Co, Cd, Mn, As, and Hg) was determined to investigate their physicochemical properties and spatial-temporal distribution characteristics. The heavy metal evaluation index (HEI) and the positive matrix factorization (PMF) model were employed to evaluate water quality and to reveal quantitatively identified pollution sources for further investigation to obtain a health risk assessment using the hazard index (HI) and carcinogenic risk (CR) of various pollution sources. The mean concentrations of heavy metal(loid)s in surface water in the wet and dry seasons were ranked as: Al > Mn > Zn > Ni > Cd > Cr > Cu > As >Hg = Pb > Co, with the mean concentration of Hg being higher than the national Class II surface water environmental quality standard (GB3838-2002). In terms of time scale, the concentration of most heavy metal(loid)s was higher in the wet season; most heavy metal(loid)s were distributed mainly in the midstream area. HEI index indicated that the main water quality status was “slightly affected” in the study area. Five potential sources of pollution were obtained from the PMF model, including industrial activities, traffic sources, agricultural activities, domestic waste emissions, and natural resources. The source-oriented risk assessment indicated that the largest contributions of HI and CR were agricultural sources in the Lijiang River. This study provides a “target” for the precise control of pollution sources, which has a broad impact on improving the fine management of the water environment in the basin.

The seasonal elevation of metals’ bioavailability can aggravate the threat of metal contamination in the aquatic environment. Nevertheless, their regulations have rarely been studied, particularly the connections between metals’ transformation and environmental variations. Therefore, the catchment area of Liujiang River was taken as an example in this study, their seasonal variations in metals’ bioavailability in sediments, especially during the wet season, was investigated to recover the processes associated with metals’ speciations and multiple environmental factors. The results revealed that the concentration of metals in sediments were high overall in the wet season, but low in the dry season. The significantly reduced ratio of metals in non-residual forms was largely related to the overall reduction in metals in oxidizable and reducible forms after the wet season. However, the elevated BI indexes of most metals suggested their increased bioavailability in the dry season, which should be closely related to their corresponding elevations in carbonate-bound and exchangeable forms after the wet season. The variations in metals’ bioavailability were primarily related to their predominance of exchangeable and carbonate-bound form. The higher correlation coefficients suggested the destabilization of the oxidizable form should be treated as a critical approach to the impact of metals’ bioavailability after the wet season. In view of that, sediments’ coarsening would pose the impacts on the destabilization of exogenous metals in sediments, the reduction in clay sediments should be responsible for the elevation of metals bioavailability after the wet season. Therefore, the monitoring of metals’ bioavailability in sediments should be indispensable to prevent metal contamination from enlarging the scope of their threat to the aquatic environment of the river, especially after the wet season.

Three high-frequency sampling and monitoring experiments were performed at the Lutang and Luowei transects of the Liujiang River entrance and at the southeast exit of the Liuzhou during 2019 for the purpose of assessing physico-chemical variables and human health hazards of water heavy metals in different rainfall processes. There were significant seasonal variations in concentrations of 11 heavy metals and most variables showed higher levels during the dry season. The distribution of heavy metals in the Liuzhou area varied significantly by region. Pollution source analysis indicated distinct seasons of wetness and dryness. The dry season is dominated by anthropogenic activities, while the wet season is dominated by natural processes. The results of hazard quotient (HQ) and carcinogenic risk (CR) analysis showed that the health risk of non-carcinogenic heavy metals in the wet season is slightly higher than that in the dry season. Seasonal changes in carcinogenic risk are the opposite; this is due to the combined influence of natural and human activities on the concentration of heavy metals in the river. Among them, Al was the most important pollutant causing non-carcinogenic, with As being a significant contributor to carcinogenic health risk. Spatially, the downstream Luowei transect has a high health risk in both the dry and rainy seasons, probably due to the fact that the Luowei transect is located within a major industrial area in the study area. There are some input points for industrial effluent discharge in the area. Therefore, high-frequency monitoring is essential to analyze and reduce the heavy metal concentrations in the Liujiang River during dry and wet seasons in order to protect the health of the residents in the area.