Solar energy is considered an essential source of energy because of cleanliness and ubiquity. However, how to effectively absorb solar energy within the range of solar radiation is an urgent problem to be solved. The design of high-performance broadband perfect absorbers is an important way to collect solar energy efficiently. In this paper, we propose a novel broadband solar energy absorber based on zinc sulfide (ZnS). It is a three-layer (Au-ZnS-Au) structure with new types of sectioned disks employed in the top layer. The sectioned disks can enhance the absorption efficiency. Surface plasmon polariton (SPP) and electric dipole resonance increase the absorption of light, so the proposed absorber can achieve broadband perfect absorption. Simulation by a finite element analysis (COMSOL) method shows that absorption with a bandwidth of 354 THz from 430 THz–784 THz has been achieved, and the average absorption is 95%. This indicates that the perfect absorption range of the proposed absorber is 78.7% of the visible range. The perfect absorber has four perfect absorption peaks, which can reach a maximum absorption rate of 99.9%. In addition, our absorber is polarization insensitive due to the design of the rotational symmetry structure of the sectioned disks. The absorber is composed of refractory metals so that it can work under actual solar radiation and high-temperature conditions. The proposed solar energy absorber is important for many applications such as solar cells, thermal photovoltaic technology, and sensing.

The Xiongcun Cu–Au ore district is in the southern middle Gangdese Metallogenic Belt, Tibet, and formed during Neo-Tethyan oceanic subduction. The Xiongcun ore district mainly comprises two deposits, the No. I and No. II deposits, which were formed by two individual mineralization events according to deposit geology and Re–Os isotopic dating of molybdenite. The No. I deposit is similar to a reduced porphyry copper–gold deposit, given the widespread occurrence of primary and/or hydrothermal pyrrhotite and common CH₄-rich and rare N₂-rich fluid inclusions. The No. II deposit, similar to classic oxidized porphyry copper–gold deposits, contains highly oxidized minerals, including magnetite, anhydrite, and hematite. The halogen chemistry of the ore-forming fluid from the No. I and No. II deposits is still unclear. Biotite geochemistry with halogen contents was used to investigate the differences in ore-forming fluid between the No. I and No. II deposits. Hydrothermal biotite from the No. I deposit, usually intergrown with sphalerite, is Mg-rich and classified as phlogopite and Mg-biotite, and hydrothermal biotite from the No. II deposit is classified as Mg-biotite. Hydrothermal biotite from the No. I deposit has significantly higher SiO₂, MnO, MgO, F, Li, Sc, Zn, Rb, Tl, and Pb contents and lower Al₂O₃, FeO_tot, Cl, Ba, Cr, V, Co, Ni, Y, Sr, Zr, Th, and Cu contents than the biotite from the No. II deposit. Hydrothermal biotites from the No. I and No. II deposits yield temperatures ranging from 230 °C to 593 °C and 212 °C to 306 °C, respectively. The calculated oxygen fugacity and fugacity ratios indicate that the hydrothermal fluid of the No. I deposit has a higher F content, oxygen fugacity, and log(fHF/fHCl) value and a lower log(fH₂O/fHF) value than the hydrothermal fluid from the No. II deposit. The biotite geochemistry shows that the No. I and No. II deposits formed from different hydrothermal fluids. The hydrothermal fluid of the No. I deposit was mixed with meteoric waters containing organic matter, resulting in a decrease in oxygen fugacity and more efficient precipitation of gold. The No. I and No. II deposits were formed by a Cl-rich hydrothermal system conducive to transporting Cu and Au. The decreasing Cl, oxygen fugacity, and temperature may be the key factors in Cu and Au precipitation. Biotite geochemistry allows a more detailed evaluation of the halogen chemistry of hydrothermal fluids and their evolution within porphyry Cu systems.