Copper matrix self-lubricating composites are critical for high-temperature industrial applications. In this study, Cu-Ni-Sn-Mo-Gr composites with 3–7 wt.% graphite were fabricated via spark plasma sintering (SPS). The influence of graphite content on microstructure, mechanical properties, and tribological behavior from room temperature (RT) to 500 °C were systematically investigated. The results demonstrate that increasing graphite content progressively reduces density, hardness, and yield strength, whereas it significantly enhances high-temperature tribological performance. The composites with 7 wt.% graphite addition achieve outstanding self-lubricity and wear resistance across the RT-500 °C, achieving an average friction coefficient of 0.09 to 0.21 and a wear rate of 1.32 × 10−6 to 7.52 × 10−5 mm3/N·m. Crucially, temperature-dependent lubrication mechanisms govern performance: graphite-dominated films enable friction reduction at RT, while synergistic hybrid films of graphite and in situ-formed metal oxides (Cu2O, CuO, NiO) sustain effective lubrication at 300–500 °C.
7 January 2019 in Anti-Corrosion Methods and Materials
Purpose: This paper aims to investigate the corrosion rate, surface morphology and composition of corrosion products of 20# seamless steel in aqueous CO2 solution under stratified gas-liquid two-phase flow condition. The development of a corrosion products layer has also been discussed. Design/methodology/approach: The following methods were used: weight loss method, scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction. Findings: The corrosion rate curve presents an irregular zigzag change trend with a gradual increase in time. The peak value of the corrosion rate appears when the corrosion time is 4 h and 8 h. The corrosion products layer is composed of two sub-layers: the inner dense layer that is about 6 µm thick and the outer loose layer that is about 9 µm thick when the corrosion time is 8 h. The main corrosion product are FeCO3 and Fe2O3. Originality/value: The atomic ratio of Fe/C/O is relatively stable for the inner dense layer, but changes in thickness for the outer loose layer. There is a densification stage after a loose corrosion products layer forms, and it is periodic.
1 October 2011 in Journal of Wuhan University of Technology-Mater. Sci. Ed.