In the current world situation, population and industrial growth have become major problems for energy and environmental concerns. Extremely noxious pollutants such as heavy metal ions, dyes, antibiotics, phenols, and pesticides in water are the main causes behind deprived water quality leading to inadequate access to clean water. In this connection, graphite carbon nitride (GCN or g-C3N4) a nonmetallic polymeric material has been utilized extensively as a visible-light-responsive photocatalyst for a variety of environmental applications. This review focuses on recent developments in the design and photocatalytic applications of metal-doped GCN-based nanomaterials in CO2 photoreduction, water splitting toward hydrogen production, bacterial disinfection, and organic pollutant degradation. Additionally, this review discusses various methods of using GCN-based materials to optimize dye sensitization, metal deposition, ion doping, and their environmental applications.
6 January 2023 in Journal of Non-Equilibrium Thermodynamics
The proposed study demonstrates the flow phenomenon and thermo-variation of a magnetized stretching sheet induced-radiative nanofluid flow. By incorporating the response surface methodology, the heat transfer rate of the thermally convective flow of nanofluid is optimized. The graphene nanomaterial is used in the water-based nanofluid. A dynamic magnetic field, thermal radiation, and the Cattaneo–Christov heat flux model have used to represent the thermal behavior of the nanofluid. The simulation utilizes experimentally estimated values for the nanomaterial’s thermal conductivity and viscosity. To further reveal the thermal enhancement of the flow, the impact of nanoparticle diameter and the solid-liquid interfacial layer is proposed at the molecular level. The response surface methodology and the sensitivity analysis has used to examine the effects of the nanoparticle volume fraction, Biot number, and magnetic parameter on the rate of heat transfer statistically. A set of equations is formed from the governing partial differential equations by implementing suitable similarity transformations. The bvp4c approach is used to solve the problem numerically. The effect of various parameters has displayed through tables, graphs, and surface plots on heat transfer, mass transfer, and the local Nusselt number. It is discovered that as the Biot number increases, so does the concentration and temperature profile. An excellent accord between the present and previously existing solutions is establishing the validity of the achieved results.
The synthesis of collagen–hydroxyapatite composites has been carried out, and the biocompatibility and osteoconductivity properties have been tested. This research was conducted to determine the ability of hydroxyapatite–collagen composites to support the bone growth through the graft surface. Hydroxyapatite used in this study was synthesized from coral with a purity of 96.6%, while collagen was extracted from the chicken claw. The process of forming a scaffold of collagen–hydroxyapatite composites was carried out using the freeze-drying method at −80°C for 4 h. The biocompatibility characteristics of the sample through the cytotoxicity tests showed that the percentage of viable cells in collagen–hydroxyapatite biocomposite was 108.2%, which is higher than the percentage of viable cells of hydroxyapatite or collagen material. When the viable cell is above 100%, collagen–hydroxyapatite composites have excellent osteoconductivity as a material for bone regeneration.