In underground engineering, cement-soil reinforcement beneath a peat soil environment is a significant challenge. To investigate the corrosiveness of fulvic acid on cement-soil and its micro and fine structure changes under the peat soil environment (PSE), an experiment was conducted to prepare peat soil by mixing humic acid (HA) into an alluvial clayey soil and then adding cement to make a cement-soil specimen, which was soaked in a fulvic acid (FA) solution and deionized water to simulate the different working of the cement-soil. The experiment was carried out by a scanning electron microscopy (SEM) test, mercury intrusion porosimetry (MIP) test, pore (particle) and fracture image recognition and analysis (PCAS), and unconfined compressive strength (UCS) test on cement-soil with soaking time as the variation factor. The results show that: In the deionized water environment, the structural characteristics of the cement-soil exhibited a gradual enhancement followed by a slight weakening. Conversely, when placed in a peat soil environment, the strength of the cement-soil initially increased at a slow rate due to the gelling and filling impact of fulvic acid. However, in the later stages, the corrosive influence of fulvic acid became dominant. This led to an enlargement of the pore space within the cement-soil, resulting in a gradual deterioration of its structure. Consequently, the strength of the cement-soil displayed a pattern of slow initial increase followed by a rapid decrease.