In this review, we survey the recent advances in nonlinear optics and the applications of two‐dimensional (2D) materials. We briefly cover the key developments pertaining to research in the nonlinear optics of graphene, the quintessential 2D material. Subsequently, we discuss the linear and nonlinear optical properties of several other 2D layered materials, including transition metal chalcogenides, black phosphorus, hexagonal boron nitride, perovskites, and topological insulators, as well as the recent progress in hybrid nanostructures containing 2D materials, such as composites with dyes, plasmonic particles, 2D crystals, and silicon integrated structures. Finally, we highlight a few representative current applications of 2D materials to photonic and optoelectronic devices.

Topological photonics has revolutionized our understanding of light propagation, providing a robust way to manipulate light. So far, most of studies in this field are focused on designing a static photonic structure. Developing a dynamic photonic topological platform to switch multiple topological functionalities at ultrafast speed is still a great challenge. Here we theoretically propose and experimentally demonstrate a reprogrammable plasmonic topological insulator, where the topological propagation route can be dynamically changed at nanosecond-level switching time, leading to an experimental demonstration of ultrafast multi-channel optical analog-digital converter. Due to the innovative use of electric switches to implement the programmability of plasmonic topological insulator, each unit cell can be encoded by dynamically controlling its digital plasmonic states while keeping its geometry and material parameters unchanged. Our reprogrammable topological plasmonic platform is fabricated by the printed circuit board technology, making it much more compatible with integrated photoelectric systems. Furthermore, due to its flexible programmability, many photonic topological functionalities can be integrated into this versatile topological platform.

We study topologically protected four-wave mixing (FWM) interactions in a plasmonic metasurface consisting of a periodic array of nanoholes in a graphene sheet, which exhibits a wide topological bandgap at terahertz frequencies upon the breaking of time reversal symmetry by a static magnetic field. We demonstrate that due to the significant nonlinearity enhancement and large life time of graphene plasmons in specific configurations, a net gain of FWM interaction of plasmonic edge states located in the topological bandgap can be achieved with a pump power of less than 10 nW. In particular, we find that the effective nonlinear edge-waveguide coefficient is about γ ≃ 1.1 × 10¹³ W⁻¹ m⁻¹, i.e., more than 10 orders of magnitude larger than that of commonly used, highly nonlinear silicon photonic nanowires. These findings could pave a new way for developing ultralow-power-consumption, highly integrated, and robust active photonic systems at deep-subwavelength scale for applications in quantum communications and information processing.

Topological photonics aims to utilize topological photonic bands and corresponding edge modes to implement robust light manipulation, which can be readily achieved in the linear regime of light-matter interaction. Importantly, unlike solid-state physics, the common test bed for new ideas in topological physics, topological photonics provides an ideal platform to study wave mixing and other nonlinear interactions. These are well-known topics in classical nonlinear optics but largely unexplored in the context of topological photonics. Here, we investigate nonlinear interactions of one-way edge modes in frequency mixing processes in topological photonic crystals. We present a detailed analysis of the band topology of two-dimensional photonic crystals with hexagonal symmetry and demonstrate that nonlinear optical processes, such as second- and third-harmonic generation, can be conveniently implemented via one-way edge modes in this setup. Moreover, we demonstrate that more exotic phenomena, such as slow-light enhancement of nonlinear interactions and harmonic generation upon interaction of backward-propagating (left-handed) edge modes, can also be realized. Our work opens up new avenues towards topology-protected frequency mixing processes in photonics.

Metasurfaces are subwavelength structured thin films consisting of arrays of units that allow the control of polarization, phase, and amplitude of light over a subwavelength thickness. Recent developments in topological photonics have greatly broadened the horizon in designing metasurfaces for novel functional applications. In this review, we summarize recent progress in the research field of topological metasurfaces, first from the perspectives of passive and active in the classical regime, and then in the quantum regime. More specifically, we begin by examining the passive topological phenomena in two-dimensional photonic systems, including both time-reversal broken systems and time-reversal preserved systems. Subsequently, we discuss the cutting-edge studies of active topological metasurfaces, including nonlinear topological metasurfaces and reconfigurable topological metasurfaces. After overviewing topological metasurfaces in the classical regime, we show how they could provide a new platform for quantum information and quantum many-body physics. Finally, we conclude and describe some challenges and future directions of this fast-evolving field.

Nonlinear topological photonics, which explores topics common to the fields of topological phases and nonlinear optics, is expected to open up a new paradigm in topological photonics. Here, we demonstrate second-harmonic generation (SHG) via nonlinear interaction of double topological valley-Hall kink modes in all-dielectric photonic crystals (PhCs). We first show that two topological frequency band gaps can be created around a pair of frequencies, ${\omega }_0$ and $2{\omega }_0$, by gapping out the corresponding Dirac points in two-dimensional honeycomb PhCs. Valley-Hall kink modes along a kink-type domain wall interface between two PhCs placed together in a mirror-symmetric manner are generated within the two frequency band gaps. Importantly, through full-wave simulations and mode dispersion analysis, we demonstrate that tunable, bidirectional phase-matched SHG via nonlinear interaction of the valley-Hall kink modes inside the two band gaps can be achieved. In particular, by using Stokes parameters associated with the magnetic part of the valley-Hall kink modes, we introduce the concept of SHG directional dichroism, which is employed to characterize optical probes for sensing chiral molecules. Our work opens up avenues toward topologically protected nonlinear frequency mixing and active photonic devices implemented in all-dielectric material platforms.