One-dimensional multiwalled carbon nanotube (MWCNT)/SiC porous nanocomposites were prepared via an in situ reaction between Si and MWCNTs induced by the reaction between Na and I2. The as-prepared nanocomposites exhibit outstanding microwave absorbing performances with an absorber thickness of about 2 mm. The absorbing bandwidth for the nanocomposites increases by raising the reaction temperature from 200 to 400 °C. The dielectric polarizations, which originate from the synergistic effect of the defects, porous structures and nanoparticles in the nanocomposites, are responsible for the excellent microwave absorbing performances.
22 October 2012 in Journal of Materials Chemistry A
Yttrium-modified Li4Ti5O12 (YLTO) was fabricated by a coprecipitation method using tetrabutyl titanate, Y(NO3)3·6H2O and LiOH·H2O as reactants, followed by simply sintering the dried mixture at 600 °C. The products and their lithiation–delithiation process were characterized by a combination of electrochemical measurements, X-ray diffraction, transmission electron microscopy and nitrogen adsorption. The YLTO exhibits excellent long-term cycling stability (over 1000 cycles) at a high current rate of 10 C and outstanding rate capabilities. Particularly, the YLTO demonstrates remarkable cyclability even if directly cycled at a rate of 10 C without low-rate activation and with no relaxation between charge and discharge. Even without utilizing carbon black as conductive material, the YLTO still shows prominent rate capabilities and long-term cyclic performance at a rate of 5 C. The excellent performance is ascribed to the increased lattice constant, improved electronic and ionic conductivities, refined grains with large surface area and uniform nanopores resulting from the Y-modification.
La-doped Li4Ti5O12 (LLTO) was prepared by a simple approach using tetrabutyl titanate, LiOH·H2O and La(NO3)3·6H2O as raw materials, followed by sintering the dried mixture at 600 °C for 5 h. Without requiring any further treatments, the as-obtained LLTO could exhibit excellent long-term cycling stability, high coulombic efficiency close to 100% at various charge–discharge rates, outstanding capacity retention at high current rates of 10–50 C, remarkable performance in the temperature range from −40 to 60 °C, good cycling performance even subjected to overcharging to about 10 times of the reversible capacity. The La-doped LTO could be directly used as efficient anode materials for lithium-ion batteries.
5 January 2017 in ACS Applied Materials & Interfaces