Leaf reflectance and transmittance spectra are essential information in many applications such as developing remote sensing methods, computing shortwave energy balance (albedo) of forest canopies, and monitoring health or stress of trees. Measurement of coniferous needle spectra has usually been carried out with single integrating spheres, which has involved a lot of tedious manual work. A small double integrating sphere would make the measurements considerably faster, because of its ease of operation and small sample sizes required. Here we applied a compact double integrating sphere setup, used previously for measurement of broad leaves, for measurement of coniferous needles. Test measurements with the double integrating sphere showed relative underestimation of needle albedo by 5â39% compared to a well-established single integrating sphere setup. A small part of the bias can be explained by the bias of the single sphere. Yet the observed bias is quite significant if absolute accuracy of measurements is required. For relative measurements, e.g. for monitoring development of needle spectra over time, the double sphere system provides notable improvement. Furthermore, it might be possible to reduce the bias by building an optimized measurement setup that minimizes absorption losses in the sample port. Our study indicates that double spheres, after some technical improvement, may provide a new and fast way to collect extensive spectral libraries of tree species.
We performed a systematic study involving simulation and experimental techniques to develop induced-junction silicon photodetectors passivated with thermally grown SiO2 and plasma-enhanced chemical vapor deposited (PECVD) SiNx thin films that show a record high quantum efficiency. We investigated PECVD SiNx passivation and optimized the film deposition conditions to minimize the recombination losses at the silicon–dielectric interface as well as optical losses. Depositions with varied process parameters were carried out on test samples, followed by measurements of minority carrier lifetime, fixed charge density, and optical absorbance and reflectance. Subsequently, the surface recombination velocity, which is the limiting factor for internal quantum deficiency (IQD), was obtained for different film depositions via 2D simulations where the measured effective lifetime, fixed charge density, and substrate parameters were used as input. The quantum deficiency of induced-junction photodiodes that would be fabricated with a surface passivation of given characteristics was then estimated using improved 3D simulation models. A batch of induced-junction photodiodes was fabricated based on the passivation optimizations performed on test samples and predictions of simulations. Photodiodes passivated with PECVD SiNx film as well as with a stack of thermally grown SiO2 and PECVD SiNx films were fabricated. The photodiodes were assembled as light-trap detector with 7-reflections and their efficiency was tested with respect to a reference Predictable Quantum Efficient Detector (PQED) of known external quantum deficiency. The preliminary measurement results show that PQEDs based on our improved photodiodes passivated with stack of SiO2/SiNx have negligible quantum deficiencies with IQDs down to 1 ppm within 30 ppm measurement uncertainty.
A goniofluorometer has been built that is capable of measuring in various viewing angles ranging from to . The incident angle can be varied from to . The goniofluorometer can measure bispectral luminescent radiance factors in the wavelength range of . To our knowledge, there are no other reported results of similar devices capable of spectral measurements in various measurement geometries.
To determine the bidirectional transmittance distribution function (BTDF) of diffusely transmitting materials, two new primary facilities have been developed at the Physikalisch-Technische Bundesanstalt (PTB) and Aalto University (Aalto). A detailed description of both facilities and the different approaches used are presented in this paper. The performance of both facilities is compared by determining the BTDF of two different diffuser types in both in-plane and out-of-plane bidirectional geometries at four different wavelengths in the visible spectral range. Due to delayed completion of PTB’s primary facility, the measured BTDF values are compared between Aalto’s primary facility and another PTB setup, whose measurement scales are successfully transferred to PTB’s primary facility by an internal comparison. A thorough analysis of the measurement uncertainty is presented, leading to a combined k = 1 standard uncertainty of 0.8%–1.2% for PTB’s primary facility and 1.3%–1.7% for Aalto’s primary facility. The BTDF results obtained agree well within their expanded k = 2 uncertainty. This indirect bilateral comparison shows that Aalto’s and PTB’s new facilities are suited as primary reference setups for the determination of the BTDF. These studies also reveal action points to improved measurement capabilities and for a reduction of the measurement uncertainty, depending on the type of diffuser under test.