The electrical conductivity of extrinsically conducting polymer composite systems passes through a transition state known as percolation threshold. A discussion has been made on how different Sigmoidal models (S-models), such as Sigmoidal–Boltzmann (SB), Sigmoidal–Dose Response (SD), Sigmoidal–Hill (SH), Sigmoidal–Logistic (SL), and Sigmoidal–Logistic-1 (SL-1), can be applied to predict the percolation threshold of electrical conductivity for ethylene vinyl acetate copolymer (EVA) and acrylonitrile butadiene copolymer (NBR) conducting composite systems filled with different carbon fillers. An interesting finding that comes from these observations is that the percolation threshold for electrical conductivity determined by SB and SD models are similar, whereas, the other models give different result when estimated for a particular composite system. This similarity and discrepancy in the results of percolation threshold have been discussed by considering the strength, weakness, and limitation of the models. The percolation threshold value for the composites has also been determined using the classical percolation theory and compared with the sigmoidal models. Moreover, to check the universal applicability, these Sigmoidal models have also been tested on results from some published literature. Finally, it is revealed that, except SL-1 model, the remaining models can successfully be used to determine the percolation threshold of electrical conductivity for extrinsically conductive polymer composites.
Textile manufacturing has been one of the highest polluting industrial sectors. It represents about one-fifth of worldwide industrial water pollution. It uses a huge number of chemicals, numerous of which are carcinogenic. The textile industry releases many harmful chemicals, such as heavy metals and formaldehyde, into water streams and soil, as well as toxic gases such as suspended particulate matter and sulphur dioxide to air. These hazardous wastes, may cause diseases and severe problems to human health such as respiratory and heart diseases. Pollution caused by the worldwide textile manufacturing units results in unimaginable harm, such as textile polymers, auxiliaries and dyes, to the environment. This review presents a systematic and comprehensive survey of all recently produced high-performance textiles; and will therefore assist a deeper understanding of technical textiles providing a bridge between manufacturer and end-user. Moreover, the achievements in advanced applications of textile material will be extensively studied. Many classes of technical textiles were proved in a variety of applications of different fields. The introductory material- and process-correlated identifications regarding raw materials and their transformation into yarns, fibers and fabrics followed by dyeing, printing, finishing of technical textiles and their further processing will be explored. Thus, the environmental impacts of technical textiles on soil, air and water are discussed.
1 February 2015 in Composites Part A: Applied Science and Manufacturing
Electrospun polymer nanofibers (EPNFs) as one-dimensional nanostructures are characterized by a high surface area-to-volume ratio, high porosity, large number of adsorption sites and high adsorption capacity. These properties nominate them to be used as an effective adsorbent for the removal of water pollutants such as heavy metals, dyes and other pollutants. Organic dyes are considered one of the most hazardous water pollutants due to their toxic effects even at very low concentrations. To overcome this problem, the adsorption technique has proven its high effectiveness towards the removal of such pollutants from aqueous systems. The use of the adsorption technique depends mainly on the properties, efficacy, cost and reusability of the adsorbent. So, the use of EPNFs as adsorbents for dye removal has received increasing attention due to their unique properties, adsorption efficiency and reusability. Moreover, the adsorption efficiency and stability of EPNFs in aqueous media can be improved via their surface modification. This review provides a relevant literature survey over the last two decades on the fabrication and surface modification of EPNFs by an electrospinning technique and their use of adsorbents for the removal of various toxic dyes from contaminated water. Factors affecting the adsorption capacity of EPNFs, the best adsorption conditions and adsorption mechanism of dyes onto the surface of various types of modified EPNFs are also discussed. Finally, the adsorption capacity, isotherm and kinetic models for describing the adsorption of dyes using modified and composite EPNFs are discussed.