To assess the mean annual groundwater recharge of the karst aquifers in the southern Apennines (Italy), the estimation of the mean annual groundwater recharge coefficient (AGRC) was conducted by means of an integrated approach based on hydrogeological, hydrological, geomorphological, land use and soil cover analyses. Starting from the hydrological budget equation, the coefficient was conceived as the ratio between the net groundwater outflow and the precipitation minus actual evapotranspiration (P − ETR) for a karst aquifer. A large part of the southern Apennines, which is covered by a meteorological network containing 40 principal karst aquifers, was studied. Using precipitation and air temperature time series gathered through monitoring stations operating in the period 1926–2012, the mean annual P − ETR was estimated, and its distribution was modelled at a regional scale by considering the orographic barrier and rain shadow effects of the Apennine chain, as well as the altitudinal control. Four sample karst aquifers with available long spring discharge time series were identified for estimating the AGRC. The resulting values were correlated with other parameters that control groundwater recharge, such as the extension of outcropping karst rocks, morphological settings, land use and covering soil type. A multiple linear regression between the AGRC, lithology and the summit plateau and endorheic areas was found. This empirical model was used to assess the AGRC and mean annual groundwater recharge in other regional karst aquifers. The coefficient was calculated as ranging between 50 and 79%, thus being comparable with other similar estimations carried out for karst aquifers of European and Mediterranean countries. The mean annual groundwater recharge for karst aquifers of the southern Apennines was assessed by these characterizations and validated by a comparison with available groundwater outflow measurements. These results represent a deeper understanding of an aspect of groundwater hydrology in karst aquifers which is fundamental for the formulation of appropriate management models of groundwater resources at a regional scale, also taking into account mitigation strategies for climate change impacts. Finally, the proposed hydrological characterizations are also supposed to be useful for the assessment of mean annual runoff over carbonate mountains, which is another important topic concerning water management in the southern Apennines.

Thus far, studies on climate change have focused mainly on the variability of the atmospheric and surface components of the hydrologic cycle, investigating the impact of this variability on the environment, especially with respect to the risks of desertification, droughts and floods. Conversely, the impacts of climate change on the recharge of aquifers and on the variability of groundwater flow have been less investigated, especially in Mediterranean karst areas whose water supply systems depend heavily upon groundwater exploitation. In this paper, long-term climatic variability and its influence on groundwater recharge were analysed by examining decadal patterns of precipitation, air temperature and spring discharges in the Campania region (southern Italy), coupled with the North Atlantic Oscillation (NAO). The time series of precipitation and air temperature were gathered over 90 yr, from 1921 to 2010, using 18 rain gauges and 9 air temperature stations with the most continuous functioning. The time series of the winter NAO index and of the discharges of 3 karst springs, selected from those feeding the major aqueducts systems, were collected for the same period. Regional normalised indexes of the precipitation, air temperature and karst spring discharges were calculated, and different methods were applied to analyse the related time series, including long-term trend analysis using smoothing numerical techniques, cross-correlation and Fourier analysis. The investigation of the normalised indexes highlighted the existence of long-term complex periodicities, from 2 to more than 30 yr, with differences in average values of up to approximately ±30% for precipitation and karst spring discharges, which were both strongly correlated with the winter NAO index. Although the effects of the North Atlantic Oscillation (NAO) had already been demonstrated in the long-term precipitation and streamflow patterns of different European countries and Mediterranean areas, the results of this study allow for the establishment of a link between a large-scale atmospheric cycle and the groundwater recharge of carbonate karst aquifers. Consequently, the winter NAO index could also be considered as a proxy to forecast the decadal variability of groundwater flow in Mediterranean karst areas.

The Chloride Mass Balance (CMB) method was used to obtain long-term recharge values for the Santa Susana Field Laboratory (SSFL) site, which features a groundwater flow system beneath an upland ridge formed of sandstone and shale beds in the Simi Hills, Ventura County, southern California. This application relied on the availability of on-site measurements of bulk atmospheric chloride deposition comprised of dry fallout and wet concentration, a large number of groundwater samples (∼1490) collected over three decades from 206 wells spanning a depth range from 10 to 360m, and measurements of chloride in surface runoff during rain events. The use of the CMB method is suited to the assessment of recharge for the study area because the mean chloride values in groundwater show minimal spatial trends, indicating no sources other than atmospheric. In addition, the Cl/Br ratio was used to exclude wells with possible anthropogenic chloride. The site-wide average recharge ranges between 1.8 and 9.5% of the mean annual precipitation (455mm) with a mean value of 4.2%. The measured surface runoff varies from 2.3 to 10.2% with mean value of 6.1% (28 mm) and, therefore, the volume of water lost to evapotranspiration is between 95.9 and 80.3% with a mean value of 89.6% (408mm). The long-term recharge calculated using the CMB method is consistent with tritium distribution based on a subset of groundwater monitoring wells and with an analysis of steady flow in the groundwater mound beneath the SSFL. Furthermore, the recharge value matches those in the literature for sandstone aquifers in arid and semi-arid climates. This recharge estimate has important relevance for site characterization in terms of constraining the volumetric groundwater flow rates and water balance and understanding the mechanisms of transport towards the water table. Moreover, this is the first application of the CMB in an upland area of California. Hence, the method is demonstrated to be robust and applicable to many upland bedrock areas in southern California and similar regions around the world, and can be used to quantify groundwater flow rates and supplies relevant to water resource management

With the aim to understand the spatial and temporal variability of groundwater recharge, a high-resolution, spatially distributed numerical model (MIKE SHE) representing surface water and groundwater was used to simulate responses to precipitation in a 2.16 km² upland catchment on fractured sandstone near Los Angeles, California. Exceptionally high temporal and spatial resolution was used for this catchment modeling: hourly climate data, a 20 m×20 m grid in the horizontal plane, and 240 numerical layers distributed vertically within the thick vadose zone and in the upper part of the groundwater zone. The finest practical spatial and temporal resolutions were selected to accommodate the large degree of surface and subsurface variability of catchment features. Physical property values for the different lithologies were assigned based on previous on-site investigations, whereas the parameters controlling streamflow and evapotranspiration were derived from calibration to continuous streamflow at the outfall and to average hydraulic heads from 17 wells. Confidence in the calibrated model was enhanced by validation through (i) comparison of simulated average recharge to estimates based on the applications of the chloride mass-balance method to data from the groundwater and vadose zones within and beyond the catchment, (ii) comparison of the water isotope signature (¹⁸O and ²H) in shallow groundwater to the variability of isotope signatures for precipitation events over an annual cycle, and (iii) comparison of simulated recharge time series and observed fluctuation of water levels. The average simulated recharge across the catchment for the period 1995–2014 is 16 mm yr⁻¹ (4 % of the average annual precipitation), which is consistent with previous estimates obtained by using the chloride mass balance method (4.2 % of the average precipitation). However, one of the most unexpected results was that local recharge was simulated to vary from 0 to >1000 mm yr⁻¹ due to episodic precipitation and overland runoff effects. This recharge occurs episodically with the major flux events at the bottom of the evapotranspiration zone, as simulated by MIKE SHE and confirmed by the isotope signatures, occurring only at the end of the rainy season. This is the first study that combines MIKE SHE simulations with the analysis of water isotopes in groundwater and rainfall to determine the timing of recharge in a sedimentary bedrock aquifer in a semiarid region. The study advances the understanding of recharge and unsaturated flow processes and enhances our ability to predict the effects of surface and subsurface features on recharge rates. This is crucial in highly heterogeneous contaminated sites because different contaminant source areas have widely varying recharge and, hence, groundwater fluxes impacting their mobility.