As a natural consequence of cosmological hierarchical structure formation, sub-parsec supermassive black hole binaries (SMBHBs) should be common in galaxies but thus far have eluded spectroscopic identification. Based on four decades of optical spectroscopic monitoring, we report that the nucleus of NGC 5548, a nearby Seyfert galaxy long suspected to have experienced a major merger about 1 billion yr ago, exhibits long-term variability with a period of ∼14 yr in the optical continuum and broad Hβ emission line. Remarkably, the double-peaked profile of Hβ shows systematic velocity changes with a similar period. These pieces of observations plausibly indicate that an SMBHB resides in the center of NGC 5548. The complex, secular variations in the line profiles can be explained by orbital motion of a binary with equal mass and a semimajor axis of ∼22 light-days (corresponding to ∼18 milli-parsec). At a distance of 75 Mpc, NGC 5548 is one of the nearest sub-parsec SMBHB candidates that offers an ideal laboratory for gravitational wave detection.

We study the long-term variability in the optical monitoring database of Ark 120, a nearby radio-quiet active galactic nucleus (AGN) at a distance of 143 Mpc (z = 0.03271). We compiled the historical archival photometric and spectroscopic data since 1974 and conducted a new two-year monitoring campaign in 2015–2017, resulting in a total temporal baseline over four decades. The long-term variations in the optical continuum exhibit a wave-like pattern and the Hβ integrated flux series varies with a similar behavior. The broad Hβ profiles have asymmetric double peaks, which change strongly with time and tend to merge into a single peak during some epochs. The period in the optical continuum determined from various period-search methods is about 20 yr, and the estimated false alarm probability with null hypothesis simulations is about 1 × 10⁻³. The overall variations of the broad Hβ profiles also follow the same period. However, the present database only covers two cycles of the suggested period, which strongly encourages continued monitoring to track more cycles and confirm the periodicity. Nevertheless, in light of the possible periodicity and the complicated Hβ profile, Ark 120 is one candidate of the nearest radio-quiet AGNs with possible periodic variability, and it is thereby a potential candidate host for a sub-parsec supermassive black hole binary.

Atomic data, such as wavelengths, spectroscopic labels, broadening parameters and transition rates, are necessary for many applications, especially in plasma diagnostics, and for interpreting the spectra of distant astrophysical objects. The experiment with its limited resources is unlikely to ever be able to provide a complete dataset on any atomic system. Instead, the bulk of the data must be calculated. Based on fundamental principles and well-justified approximations, theoretical atomic physics derives and implements algorithms and computational procedures that yield the desired data. We review progress and recent developments in fully-relativistic multiconfiguration Dirac–Hartree–Fock methods and show how large-scale calculations can give transition energies of spectroscopic accuracy, i.e., with an accuracy comparable to the one obtained from observations, as well as transition rates with estimated uncertainties of a few percent for a broad range of ions. Finally, we discuss further developments and challenges.

Combined relativistic configuration interaction and many-body perturbation calculations are performed for the 359 fine-structure levels of the 2s ² 2p ³, 2 s2p ⁴, 2p ⁵, 2s ² 2p ² 3l, 2 s2p ³ 3l, 2p ⁴ 3l, and 2s ² 2p ² 4l configurations in N-like ions from Ar xii to Zn xxiv. Complete and consistent data sets of energies, wavelengths, radiative rates, oscillator strengths, and line strengths for all possible electric dipole, magnetic dipole, electric quadrupole, and magnetic quadrupole transitions among the 359 levels are given for each ion. The present work significantly increases the amount of accurate data for ions in the nitrogen-like sequence, and the accuracy of the energy levels is high enough to enable the identification and interpretation of observed spectra involving the n = 3, 4 levels, for which experimental values are largely scarce. Meanwhile, the results should be of great help for modeling and diagnosing astrophysical and fusion plasmas.