Physical mechanisms of both classical and quantum nature, which can in principle activate biochemical kinetics of solutions, are discussed. The generation
The mechanisms of time-dependent impacts of classical nature (mechanical, magnetic, and electric) on quantum particles, including spin ones, have been theo
A compact laser scatterometric device for determining the fat percentage of milk filling a cylindrical tube has been designed. The device operates by detecting the angular distribution of the scattered radiation of a semiconductor laser using an axial array of photodiodes. We have experimentally found that the light-scattering indicatrix in cow milk has a monotonous dependence on milk fat content. The intensity at side- or forward-scattering angles normalized to the backscattering intensity proves to be a reliable, informative parameter. A polynomial approximation for the calibration curve of fat percentage versus normalized scattering intensity is constructed to enable fat content measurements in the fairly wide range of ~0.01–10%. Furthermore, the intensity at forward scattering angles responds to the presence of large-scale particles in milk. The device was tested in a laminar flow regime at milk flow rates up to 100 mL/s.
A monoblock light-scattering sensor, which is capable of measuring the fat content of milk and indicating the excess by which the somatic cell count (SCC) is over the permissible level, has been developed for installation in dairy systems. In order for the sensor to perform measurements when the milking machine is working in the “milk plug” mode, a flow-through unit is designed in the form of a pipe with a lateral cylindrical branch, in which milk accumulates so as to eliminate large bubbles and achieve continuity of the milk flow. The operation of the sensor is based on the registration of the angular intensity distribution of light scattered in the transparent cylindrical segment of the tube branch. A semiconductor laser with a wavelength of 650 nm is used as a light source for determining scattering in milk. The angular distribution of the scattered light intensity (scattering indicatrix) is recorded using an axial photodiode array. The fat content is determined by the average slope of the measured scattering indicatrix in the range of scattering angles 72–162°. The SCC level is estimated from the relative deviation of the forward scatter intensity normalized to the backscatter intensity with respect to uninfected milk. The sensor has been tested on a Yolochka-type milking machine.
A system of kinetic equations describing the changes in the concentration of reactive oxygen species (ROS) in aqueous solutions of proteins was obtained from the analysis of chemical reactions involving singlet oxygen. Applying the condition of the stationarity of the intermediate products to the system, we determined the functional dependence of the hydrogen peroxide concentration on the protein concentration under the action of thermal and laser radiation. An approximate analytical solution to the nonlinear system of differential equations that define the ROS concentration dynamics was found. For aqueous solutions of bovine serum albumin (BSA) and bovine gamma globulin (BGG), the orders and rate constants of the reactions describing the ROS conversions were determined by minimizing the sum of squared deviations of the functions found by solving both the static and dynamic problems from experimentally measured dependences. When solving the optimization problem, the Levenberg–Marquardt algorithm was used.