The characteristics of laminae are critical to lacustrine shale strata. They are the keys to the quality of source rocks and reservoirs, as well as engineering operations in shale plays. This study uses organic geochemistry, thin section identification, X-ray diffraction, field emission scanning electron microscopy, and other analytical methods, to reveal the detailed lamination texture and vertical distribution of laminae in the second Member of the Kongdian Formation in Cangdong Sag. The principal results are as follows: (1) A classification of laminae is proposed to characterize reservoir and geochemical properties. The five types of laminae are as follows: feldspar-quartz laminae (FQL), clay laminae (CLL), carbonate laminae (CAL), organic matter laminae (OML), and bioclastic laminae (BCL). There are also four significant lamina combinations (with the increasing TOC values): FQL-CLL combination, FQL-CLL-BCL combination, FQL-CLL-OML combination, and FQL-CAL-CLL-OML combination; (2) differences between laminae occur because of the variability in pore types and structures. There appears to be a greater abundance of intercrystalline pores of clay minerals in the FQL, CAL, BCL, and OML, and well-developed organic pores in the CAL and CLL, and the counterparts of intragranular pores of bioclastic material in the BCL. This detailed characterization provides the following comparative quantification of the thin section porosity of laminae in the second Member of the Kongdian Formation can be differentiated: CAL > FQL > OML > BCL > CLL; (3) differentiation between vertical distributions of laminae is carried out in a single well. The FQL and CLL are widely distributed in all the samples, while the BCL is concentrated in the upper part of the second Member of the Kongdian Formation, and CAL is concentrated in the lower part. This detailed classification method, using geochemical analysis and vertical distribution descriptions, offers a detailed understanding of lamination texture and its effects on reservoir and geochemical properties, which will provide a scientific guidance and technical support to better estimate reservoir quality and to identify new sweet spots in the second Member of the Kongdian Formation in the Cangdong Sag.

The organic-rich shale of the Qingshankou Formation (K₂qn) is the most important target in the Songliao Basin. The relationship between lithofacies and source rock quality, however, is still controversial. Core observation, thin section identification, X-ray diffraction, organic geochemistry, and other analytical methods were adopted to investigate the petrology and its effects on hydrocarbon potential of the Qingshankou shale. Based on the differences in minerals, bioclastic, and fabric of laminae, four main lithofacies were defined as: (i) felsic shale (FS), (ii) clay shale (CS), (iii) bio-bearing shale (BS), and (iv) mixed shale (MS). The clay minerals content in the CS (average: 46.72 wt%) and MS (average: 41.11 wt%) was higher than that in FS (average: 39.97 wt%) and BS (average: 35.48 wt%). This classification allows the following comparative quantification of total organic carbon (TOC) content to be differentiated: CS > BS > MS > FS. Geochemical analysis indicated that the oil generation potential of the CS was the best, and the hydrocarbons generated from CS might migrate and accumulate in other lithofacies. All this knowledge could shed light on the lithofacies classification in shale systems with high clay mineral content, and may provide references for sweet spotting of the Qingshankou Formation in the Songliao Basin.

The origin of the organic-rich shale in the Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation is complex and controversial. This paper reports the geochemical data of Wufeng-Longmaxi Formations in the Upper Yangtze region to restore the paleoenvironment and explore the accumulation mechanism of organic matter. The total organic carbon (TOC) content of the Wufeng Formation was relatively high, with an average of 2.86%. The Lower Longmaxi Formation showed the highest TOC content, with an average of 3.99%, and the upper part was a continuously low value with an average of 1.22%. The paleoproductivity proxies (Ba_bio, Cu/Al, Ni/Al, Si_excess) showed that in the Katian and Rhuddanian-Aeronian Stages, the Upper Yangtze Sea had high primary productivity, indicating that organic matter accumulation was more affected by terrigenous influx and redox conditions. Al, Zr, and Zr/Al indicated that terrigenous influx was relatively high in the Kaitian-Hirnantian Stages, it was at a constant low in the Rhuddanian Stage, and increased again in the Aeronian Stage. The correlations between redox-sensitive trace elements (Mo, U, V) and TOC indicate that the organic-rich shale of the Wufeng Formation was deposited in the anoxic–euxinic environment. In the Longmaxi Formation, organic-rich shales formed in a more hypoxic environment, and overlying organic-lean shales formed in a suboxic environment. Therefore, the anoxic–euxinic conditions of the Late Ordovician Yangtze Sea were the main reason for the organic matter accumulation, but the high terrigenous influx caused by regression and/or structural controls diluted the organic matter to some extent. For the Early Silurian, a complete transgression–regression cycle changed terrigenous influx and redox conditions, resulting in significant differences in organic matter accumulation.

In this work, the potential influences of grain-coating clays on water-CO₂-rock interactions in sandstones and subsequent ramifications for CO₂ storage were investigated using reactive transport simulations. The results indicated that, compared to pore-filling smectite, grain-coating smectite leads to significant pH decrease, increases in the CO₂-species concentrations, and decreases in smectite dissolution and the precipitation of secondary minerals. Moreover, it was revealed that smectite and chlorite coats dissolve preferentially over detrital K-feldspar being covered, while K-feldspar is dissolved preferentially over illite and kaolinite coats. While the mineral trapping mechanism is only important for smectite and chlorite coats, sandstone porosity is significantly reduced for chlorite coat but increased for the other three clay coats. The main causes of the differences between pore-filling and grain-coating scenarios for smectite and chlorite coats are ascribed to the inhibitory effect of clay coats on the growth of secondary quartz and the dissolution of clay. In addition to the above two factors, the decelerating effect of clay coats on the dissolution of K-feldspar is also important for illite coat; meanwhile, for the kaolinite coat, the dissolution of clay is less important and the other two factors are more critical. Furthermore, the coverage and thickness of clay coats, fluid flow rate, detrital grain size, detrital lithology, partial pressure of CO₂, and temperature may all impact the role of clay coats. Document Type: Original article Cited as: Li, H., Hu, Q., Zhu, R., Liu, B., Mishara, A., Ansah, E. O. Reactive transport modeling of water-CO₂-rock interactions in clay-coated sandstones and implications for CO₂ storage. Advances in Geo-Energy Research, 2025, 17(2): 121-134. https://doi.org/10.46690/ager.2025.08.04