New carbazole- and terpyridine- containing norbornene derivatives were synthesized and structurally characterized. On the basis of these compounds by the method of metathesis polymerization copolymers were obtained with carbazole and terpyridine fragments in side chains. The synthesized copolymers react with terbium pyrazolonate complex to form the terbium-containing polymeric materials exhibiting the metalcentered photo- and electroluminescence.