As an alternative route for aromatics and hydrogen production, methane dehydroaromatization (MDA) is of significant academic and industrial interest due to the abundance of natural gas resources and the intensive demand for aromatics and COx-free hydrogen. In the present work, a simulation study on MDA in membrane reactors (MRs) was performed with the aim of co-producing aromatics and COx-free hydrogen with a highly improved efficiency. The effects of various parameters, including catalytic activity, membrane flux and selectivity, as well as the operating conditions on the MR performance were discussed with respect to methane conversion, hydrogen yield, and hydrogen purity. The results show that catalytic activity and membrane flux and selectivity have significant impacts on CH4 conversion and H2 yield, whereas H2 purity is mainly dominated by membrane selectivity. A highly improved MDA is confirmed to be feasible at a relatively low temperature and a high feed pressure because of the hydrogen extraction effect. To further improve MDA in MRs by intensifying H2 extraction, a simple configuration combining a fixed-bed reactor (FBR) and an MR together is proposed for MDA, which demonstrates good potential for the high-efficiency co-production of aromatics and COx-free hydrogen.
For the application of hybrid tasks in priority-based preemptive systems, an innovative two-level hierarchical scheduling scheme is presented, and the time-triggered mode and event-triggered mode are adopted for the periodic real-time tasks and aperiodic real-time tasks respectively. First, the scheduling structure is proposed and the related concepts are defined. Then, the task model is established, and some crucial technologies such as scheduling algorithm, schedulability and jitter control are deeply researched. Subsequently, combined with Windows CE.NET, the experiment validation of scheduling scheme is carried out and the results demonstrate that the method can improve the determination of real-time tasks and reduce jitter. Specially, the jitter can be even eliminated if the task periods and tick-interval are rational. Finally, the choice of tick-interval is discussed. So the proposed scheduling scheme is efficient for hybrid tasks.
Conventional high-temperature calcination for activating MFI zeolite membranes is energy-intensive and prone to inducing defects. Here, we demonstrate that a rapid ozonation treatment at 200 °C for only 1 h effectively decomposes organic templates while preserving membrane integrity. The resulting membrane exhibits H2/CH4 and H2/N2 ideal selectivities of 10.3 and 6.5, respectively, at room temperature, with C3H8 and SF6 permeances below the detection limit. These results confirm a dense, defect-minimized architecture and good molecular sieving performance of the zeolite membrane. In contrast, extending ozonation to 48 h leads to defect formation and a marked reduction in selectivity. For H2/CH4 mixture separation, the membrane achieves a selectivity of 23.8 at 100 °C, which is highly competitive among reported MFI membranes. In isopropanol dehydration, it achieves a water flux of 2.3 kg·m−2·h−1 and a separation factor of 3278 at 70 °C with a 10 wt% water feed, while maintaining >99.5 wt% water content in the permeate over a broad operating temperature range (30–70 °C). This work establishes rapid ozonation as a scalable, energy-efficient activation method for high-performance MFI zeolite membranes in both gas and liquid separations.